Photopolymerizable composition
AssigneeFuji Photo Film Co., Ltd.
InventorsSadao Fujikura, Masayuki Iwasaki, Yuichi Wakata
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Abstract
A photopolymerizable composition developable with an alkali aqueous solution which comprises a carboxyl group-containing high polymer binder, a photopolymerizable monomer, a photopolymerization initiator system and a compound of a specific structure is disclosed. The photopolymerizable composition shows a good keeping stability in a state of lamination on a metal board and thus is highly useful in the production of, for example, dry films for print basic boards, photoresists, photomasks, lithograph boards and resin relief boards.
Claims3
A photopolymerizable composition developable with an alkali aqueous solution which comprises:
- (1) a carboxyl group-containing high polymer binder having the weight-average molecular weight of 5,000 to 2,000,000 in the amount of 40 to 90% by weight;
- (2) a photopolymerizable monomer in the amount of 10 to 60% by weight;
- (3) a photopolymerization initiator system comprising a lophine dimer in the amount of 0.1 to 20% by weight;
- and
- (4) at least one compound selected from the group consisting of compound represented by the general formulae (I), (II) and (III) in the amount of 0.1 to 10% by weight:
- wherein R.sup.1 to R.sup.10 may be either the same or different and each represents H, NR.sup.11.sub.2, OR.sup.11, SR.sup.11, COOR.sup.11, CN a halogen atom, NO.sub.2, CHO, SO.sub.3 R.sup.11, R.sup.11 CONHNH, R.sup.11 SO.sub.2 NH, an aryl group having 6 to 10 carbon atoms, an alkyl group having 1 to 10 carbon atoms, an aminoalkyl group having 1 to 10 carbon atoms, a hydroxyalkyl group having 1 to 10 carbon atoms, a carboxyalkyl group having 1 to 10 carbon atoms, an aralkyl group having 7 to 20 carbon atoms or a monophorino group;
- Y represents an alkylene group having 1 to 10 carbon atoms, an arylene group having 6 to 12 carbon atoms or an aralkylene group having 7 to 25 carbon atoms which may be substituted by NR.sup.11.sub.2, OR.sup.11, SR.sup.11, COOR.sup.11, CN, a halogen atom, NO.sub.2, CHO, SO.sub.3 R.sup.11, R.sup.11 CONHNH, R.sup.11 SO.sub.2 NH, or a monophorino group, and which may contain between two carbon atoms a bivalent intervenient group of pyperadine residue, COO, NR.sup.11, SO.sub.2, SO.sub.2 NR.sup.11, O, S, CONR.sup.11, CONHCO or COONR.sup.11 ;
- wherein R.sup.11 represents H, an alkyl group having 1 to 10 carbon atoms or an aryl group having 6 to 10 carbon atoms.
Dependencies are inferred from the claim text.