Fluorine-containing graft copolymer and toner using the same
AssigneeRicoh Company, Ltd.
InventorsTsubuko Kazuo, Shinichi Kuramoto, Kazuhiko Umemura, Toshihiko Takahashi, Hidemi Uematsu
Life of this patent
Estimating the term…
Loading patent…
AssigneeRicoh Company, Ltd.
InventorsTsubuko Kazuo, Shinichi Kuramoto, Kazuhiko Umemura, Toshihiko Takahashi, Hidemi Uematsu
Estimating the term…
A fluorine-containing graft copolymer prepared by a step (i) of polymerizing a monomer having formula (I) and an unsaturated carboxylic acid or a monomer having a glycidyl group to obtain a copolymer, ##STR1## wherein R represents --H or --CH.sub.3 group; and A represents --COOC.sub.n H.sub.2n+1 or OC.sub.n H.sub.2n+1, in which n is an integer of 6 to 20; a step (ii) of esterifying the resulting copolymer by using a monomer having a glycidyl group in the case where a constituting monomer of the above copolymer is an unsaturated carboxylic acid, or by using an unsaturated carboxylic acid in the case where a constituting monomer of the above copolymer is a monomer having a glycidyl group; and a step (iii) of graft-polymerizing a monomer comprising at least fluoroalkyl acrylate or fluoroalkyl methacrylate on the above esterified copolymer. In addition, a toner comprising a coloring agent and a resin component which comprises the above-mentioned fluorine-containing graft copolymer is disclosed.
A dry-type toner comprising a coloring agent, and a resin component which comprises a fluorine-containing graft copolymer prepared by a step (i) of polymerizing a monomer having formula (I) and an unsaturated carboxylic acid or an acrylic monomer having a glycidyl group to obtain a copolymer, ##STR15## wherein R represents --H or --CH.sub.3 group;
A wet-type developer comprising (a) a toner component which comprises a coloring agent and a resin component which comprises a fluorine-containing graft copolymer prepared by a step (i) of polymerizing a monomer having formula (I) and an unsaturated carboxylic acid or an acrylic monomer having a glycidyl group to obtain a copolymer, ##STR16## wherein R represents --H or --CH.sub.3 group;
Dependencies are inferred from the claim text.