Microporous membrane from cold-rolled precusor film
AssigneeHoechst Celanese Corporation
InventorGunilla E. Gillberg-LaForce
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Abstract
The process for forming a microporous polymeric semi-crystalline film, involving the steps of cold compressive extruding a precursor film, preferably in a biaxial fashion, so as to compress the film by a factor of about 2 to 1 to about 10 to 1, stretching the film by about 100 to about 500 percent, preferably in a biaxial fashion, and heat annealing either before, during, or preferably after the stretching step at a temperature up to the alpha transition temperature of the polymer for a time sufficient to maintain the microporous character of the final film.
Claims11
A microporous film comprising a thermoplastic, semi-crystalline polymer, said film having an average pore size of from about 10 to about 100 nanometers and having a thickness of from about 3 to about 10 mils.
A microporous film comprising a thermoplastic, semicrystalline polymer, said film having an average pore size of from about 20 to about 30 nanometers and having a thickness of from about 3 to about 10 mils, said film being made by the process of:
- cold compressing a precursor film comprising said polymer to reduce the thickness thereof by a factor in the approximate range of from 3:1 to 8:1 to form a compressed film;
- and,
- biaxially stretching said compressed film from about 200% to about 300% to impart microporosity to said film.
Dependencies are inferred from the claim text.