Method for purification of lean-burn engine exhaust gas
AssigneeFord Motor Company
InventorsClifford Montreuil, Haren S. Gandhi, Mohinder S. Chattha
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Abstract
A dual-phase zeolite having a transition metal-containing zeolite phase and a transition metal-containing oxide phase. The catalytic material may be an intimate mixture of a phase-layered structure of a first phase constituted preferably of a copper-containing high silica zeolite and a second phase constituted of copper-containing zirconia. Methods are also disclosed for making a single-stage catalyst for removing NO.sub.x and HC at high efficiency in an oxygen-rich automotive exhaust gas, and for treating the exhaust gas with the dual-phase catalyst above.
Claims2
A method of treating automotive exhaust gases to remove NO.sub.x, CO, and HC, comprising:
- (i) operating an internal combustion engine to produce an exhaust gas having a NO.sub.x, CO, and no less than 1500 ppm HC content;
- (ii) exposing a dual-phase catalyst to substantially the entire through-flow of said exhaust as at a space velocity 20-60 K hr.sup.-1 to obtain NO.sub.x conversion efficiency of at least 50% and an HC conversion efficiency of at least 98%, said dual phase catalyst comprising a first phase consisting of copper containing zirconium oxide, and the second phase consisting of a zeolite that is ion-exchanged with copper, said first phase having zirconia present in an amount of 0.1-20% by weight of the catalyst and ion-exchanged copper being present in said second phase in an amount of at least 3% up to a maximum determined by the SiO.sub.2 /Al.sub.2 O.sub.3 ratio of the zeolite.
Dependencies are inferred from the claim text.