# US 5,328,659 A · Superalloy heat treatment for promoting crack growth resistance > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 5,328,659 A - Document ID: US5328659A - Status: Granted - Kind: A - Application number: 06/733,446 - Filed: 1985-05-10 - Granted: 1994-07-12 - Earliest claimed: 1982-10-15 - Assignees: United Technologies Corporation - Inventors: Thomas D. Tillman; John M. Robertson; Arthur R. Cox - Web page: https://patentgrep.com/patent/US5328659A ## CPC - C22F 1/10: of nickel or cobalt or alloys based thereon - C22C 19/056: {with the maximum Cr content being at least 10% but less than 20%} - C22F: CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS (surface treatment of metallic material involving at least one process provided for in class C23 and at least one process covered by this subclass, C23F17/00) - C22C: ALLOYS (treatment of alloys C21D, C22F) ## Abstract Nickel base superalloy articles, especially gas turbine disks, are provided with substantially enhanced resistance to crack growth through a specific heat treatment. The heat treatment employs a true solution treatment step followed by a subsolvus solution treatment step, followed by at least one aging step. The effect of this series of heat treatment steps is to provide a microstructure having an optimum arrangement of gamma prime particles, with respect to both size and location. Reductions in crack growth rates of several hundred percent relative to prior art heat treatments are achieved. ## Claims ### Claim 1 A heat treatment for reducing the crack growth rate in superalloy articles which consist essentially of 12-15.5% chromium, 8-19% cobalt, 2-4.5% titanium, 3.2-5.2% aluminum, 2.8-5.4% molybdenum, 0.01-0.1% carbon, 0-0.08% zirconium, 0.005-0.024% boron, 0-1% vanadium, 0-4% tantalum, 0-1.5% columbium, 0-0.45% hafnium, 0-4% tungsten, balance nickel, which consists of: (a) solution treating the article at a temperature between the gamma prime solvus and the incipient melting temperature for a time of about 1 to 10 hours; (b) cooling the article at a rate between about 100.degree. F. (56.degree. C.) and about 300.degree. F. (167.degree. C.) per hour to a temperature between about 200.degree. F. (111.degree. C.) and about 400.degree. F. (222.degree. C.) below the gamma prime solvus; (c) cooling the article to below about 500.degree. F. (260.degree. C.) at a rate greater than about 100.degree. F. (56.degree. C.)/min; (d) heating the article to a temperature about 30.degree. F. (17.degree. C.) to about 200.degree. F. (111.degree. C.) below the gamma prime solvus and holding at this temperature for about 1 to 10 hours; (e) cooling the article to below about 500.degree. F. (260.degree. C.) at a rate in excess of about 100.degree. F. (56.degree. C.)/min; and (f) aging at one or more temperatures between about 800.degree. F. (427.degree. C.) and about 1800.degree. F. (982.degree. C.) for a total time of about 3 to 50 hours. ### Claim 2 (depends on 1) A heat treatment as in claim 1 wherein the superalloy has a nominal composition of about 12.4% chromium, 18.5% cobalt, 4.3% titanium, 5.0 aluminum, 3.2 molybdenum, 0.07 carbon, 0.8% vanadium, 0.06% zirconium, 0.02% boron, balance nickel. ### Claim 3 (depends on 1) A heat treatment as in claim 1 wherein the superalloy has a nominal composition of about 14.0% chromium, 8.0% cobalt, 2.5% titanium, 3.5% aluminum, 3.5% molybdenum, 0.15% carbon, 0.05% zirconium, 0.01% boron, 3.5% tantalum, 3.5% tungsten, balance nickel. ### Claim 4 (depends on 1) A heat treatment as in claim 1 wherein the superalloy has a nominal composition of about 15.0% chromium, 17.0% cobalt, 3.5% titanium, 4.0% aluminum, 5.0% molybdenum, 0.06% carbon, 0.03 boron, balance nickel. ### Claim 5 (depends on 1) A heat treatment as in claim 1 in which the cooling rate in step (b) is from about 150.degree. F. (83.degree. C.) to about 250.degree. F. (139.degree. C.)/hour. ### Claim 6 A heat treated superalloy article consisting essentially of 12.4% chromium, 18.5% cobalt, 4.3% titanium, 5.0% aluminum, 3.2% molybdenum, 0.07% carbon, 0.8% vanadium, 0.06% zirconium, 0.02% boron, balance nickel, having a grain size of 20-90 microns, and containing a triplex distribution of gamma prime particles with about 6% by volume having a size of about 2-4 microns, about 40% by volume having a size of about 0.7-0.9 microns and about 54% by volume having a size of less than about 0.2 micron. ### Claim 7 (depends on 1) A superalloy article heat treated according to claim 1.