Stabilized grafted ethylene copolymer additive useful in oil compositions
AssigneeExxon Chemical Patents Inc.
InventorDavid Y. Chung
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AssigneeExxon Chemical Patents Inc.
InventorDavid Y. Chung
Estimating the term…
Oil-soluble, derivatized ethylene copolymers derived from about 15 to 90 wt. % ethylene, and one or more C.sub.3 to C.sub.28 alpha-olefins, e.g. propylene, which are grafted, preferably solution-grafted under an inert atmosphere and at elevated temperatures and in the presence of a high-temperature decomposable free-radical initiator, with an ethylenically-unsaturated dicarboxylic acid material and thereafter reacted with a polyamine having at least two primary amine groups, e.g. an alkylene polyamine such as diethylene triamine, to form carboxyl-grafted polymeric imide, usually maleimide, derivatives are subsequently reacted with a C.sub.12 to about C.sub.18 hydrocarbyl substituted dicarboxylic acid anhydride, preferably a C.sub.12 to about C.sub.18 hydrocarbyl substituted succinic anhydride, to yield an oil-soluble stable imide of said carboxyl-grafted copolymeric imide whereby oil solutions thereof are characterized by minimal viscosity change over an extended period of time. Useful number average molecular weights (M.sub.n) of said copolymers range from about 700 to 500,000; however, if the molecular weight is from about 10,000 to 500,000 then these copolymers are also useful as multi-functional viscosity index improvers.
An oil soluble additive consisting essentially of reaction product of:
A process for improving the viscosity stability of a lubricating oil composition containing lubricating oil and an oil soluble reactive nitrogen containing grafted ethylene copolymer oil additive which is the reaction product of:
An oil soluble reactive nitrogen containing grafted ethylene copolymer useful as a lubricating oil additive prepared by a process comprising:
Dependencies are inferred from the claim text.