Homogeneous catalytic hydrodechlorination of chlorocarbons
AssigneeE. I. Du Pont de Nemours and Company
InventorRalph T. Baker
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Abstract
This invention relates to a liquid phase process for the preparation of R.sub.f CHXY by the homogeneous catalytic hydrodechlorination of R.sub.f CClXY wherein X and Y are independently H, F, Cl or R.sub.f ' provided X and Y are not both Cl, R.sub.f and R.sub.f ' are independently F, CF.sub.3, (CF.sub.2).sub.n Cl or (CF.sub.2).sub.n CF.sub.3, and n is 1-4, by reacting the R.sub.f CClXY with hydrogen while in solution with a Periodic Table Group 6-10 metal complex catalyst which contains tertiary Periodic Table Group 15 ligands without added base.
Claims8
A liquid phase process for the homogeneous catalytic hydrodechlorination of a compound having the formula R.sub.f CClXY wherein X and Y are independently H, F, Cl or R.sub.f ' provided X and Y are not both Cl;
- R.sub.f and R.sub.f ' are independently F, CF.sub.3, (CF.sub.2).sub.n Cl or (CF.sub.2).sub.n CF.sub.3, and n is 1-4, which comprises reacting the compound with hydrogen while in solution with a Periodic Table Group 6-10 metal complex hydrodechlorination catalyst containing tertiary Periodic Table Group 15 ligands, without added base, to form R.sub.f CHXY, wherein the Periodic Table Group 6-10 metal is selected from Re, Mo, W, Fe, Ru, Os, Co, Rh, Ir, Ni, Pd, and Pt, with the tertiary Periodic Table Group 15 ligand selected from phosphine, arsine, stibine, and bismuthine.
A process according to claim 2 wherein the temperature is from about 80.degree. to about 200.degree. C. and the pressure is from about 100 to about 1000 psi.
A liquid phase process for the homogeneous catalytic hydrodechlorination of CFCl.sub.2 CF.sub.3 which comprises reacting CFCl.sub.2 CF.sub.3 with H.sub.2 in a benzene solution with a {RhCl[1,2-(Pr.sup.i.sub.2 P).sub.2 C.sub.6 H.sub.4 ]} catalyst at an initial pressure of 100 psi and a temperature of 150.degree. C. to form CH.sub.2 FCH.sub.3.
A liquid phase process for the catalytic hydrodechlorination of CFCl.sub.2 CF.sub.3 which comprises reacting neat CFCl.sub.2 CF.sub.3 with H.sub.2 with {RhCl[Pr.sup.i.sub.2 P(CH.sub.2).sub.3 PPr.sup.i.sub.2 ]}.sub.2 at an initial pressure of 500 psi at a temperature of 120.degree. C. to form CH.sub.2 FCF.sub.3.
Dependencies are inferred from the claim text.