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US 5,326,818 AGranted
Polysiloxanic stabilizers containing sterically hindered phenol groups and reactive groups
AssigneeEni Chem Synthesis S.p.A.
InventorsLuciano Pallini, Daniele Fabbri, Rossella Farris, Carlo Neri
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Abstract
Polymeric stabilizers with a polysiloxanic structure contain sterically hindered phenol groups and reactive groups capable of binding themselves to the polymeric structure to be stabilized. These polymeric stabilizers are particularly suitable for applications which require the non-extractability of additives due to solvents, fats or soaps.
Claims20
A polymeric composition comprising an organic polymer and a stabilizing quantity of a polymeric stabilizer having a formula:
- MX.sub.m Y.sub.p Z.sub.q M'
- wherein ##STR19## M' is --OM, M and M' can optionally form together a direct bond thus producing a cyclic structure,
- R.sub.1 is a phenyl or a linear or branched alkyl radical containing from 1 to 20 carbon atoms,
- R.sub.2 is a reactive organic group which contains a carbon-carbon double bond, an epoxy ring, a sulfide group, or an aminic group,
- R.sub.3 is a linear or branched alkyl radical containing from 1 to 6 carbon atoms,
- R.sub.4 is a radical selected from the group consisting of ##STR20## wherein, R.sub.5 and R.sub.6, which may be the same or different, are linear or branched alkyl radicals which contain from 1 to 10 carbon atoms,
- R.sub.7 is a linear or branched alkylene radical which contains from 3 to 10 carbon atoms,
- R.sub.8 is a linear or branched alkylene radical which contains from 1 to 10 carbon atoms or a biradical selected from the group consisting of --R.sub.9 --COO--R.sub.10, --R.sub.9 --COO--R.sub.11 --,
- R.sub.9, R.sub.10 and R.sub.11, which may be the same or different, are linear or branched alkylene radicals which contain from 2 to 10 carbon atoms,
- R' is a phenyl or a linear or branched alkyl radical which contains from 1 to 10 carbon atoms,
- R" is the same as R', R.sub.2 or R.sub.4,
- m and p, which may be the same or different, are integers from 1 to 50, and
- q is an integer between 0 and 50,
- n is equal to 0 or 1.
11 more elements
Dependencies are inferred from the claim text.