Thermal transfer image-receiving material
AssigneeFuji Photo Film Co., Ltd.
InventorsTetsu Kamosaki, Mitsugu Tanaka, Masakazu Yoneyama
Life of this patent
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Abstract
A thermal transfer image-receiving material having an image-receiving layer comprising a thermoplastic resin capable of receiving a dye, on a support, wherein the thermoplastic resin is a polyester having anti-fading groups in at least one of a main chain and a side chain moiety of the molecular structure of the thermoplastic resin and the material has the ability to form an image with a high image density and excellent image storage stability by thermal transfer recording.
Claims18
A thermal transfer image-receiving material having an image-receiving layer comprising a thermoplastic resin capable of receiving a dye, on a support, wherein the thermoplastic resin is a polyester obtained by poly-condensation of monomers represented by formula (1), (2), (3) and (4) of monomers represented by formula (1), (2), (5) and (6):
- ##STR24## where A.sub.1 and A.sub.2 each represents a substituted or unsubstituted alkylene, arylene or cycloalkylene group having from 1 to 18 carbon atoms and may be the same or different;
- A.sub.3 and A.sub.4 each represents a substituted or unsubstituted alkylene or arylene group having from 1 to 18 carbon atoms and may be the same or different;
- B.sub.1, B.sub.2, B.sub.3, B.sub.5 and B.sub.4 each represents a hydrogen atom or a substituted or unsubstituted alkyl group having from 1 to 8 carbon atoms and may be the same or different;
- L.sub.1 and L.sub.2 each represents a linking group capable of bonding adjacent groups via a bonding group of ether, ester, amido or urethane and may be the same or different;
- a and b each represents 1 or 2 and may be the same or different, M.sub.1 and M.sub.2 each represents an anti-fading group of formula (7) and may be the same or different:
- ##STR25## wherein R.sup.1 represents a hydrogen atom, or a substituted or unsubstituted alkyl, alkenyl, aryl, heterocyclic or silyl group having from 1 to 21 carbon atoms;
- and if l is more than 1, the more than one R.sup.1 's may be same or different from each other;
- X.sup.1 represents --O--, --S-- or .dbd.N--R.sup.(1) wherein R.sup.(1) is a hydrogen atom or a substituted or unsubstituted alkyl or aryl group having up to 18 carbon atoms;
- when X.sup.1 is --O-- and R.sup.1 is an alkyl group, then if two adjacent --OR.sup.1 groups are present, the two adjacent --OR.sup.1 groups may be bonded to each other to form a methylene or ethylene group;
- X.sup.2 represents a bonding group of ether, ester, amido or urethane;
- l represents a number from 1 to 3;
- and
- R.sup.2, R.sup.3, R.sup.4 and R.sup.5 each represents a hydrogen atom, an organic residue or [R.sup.1 --X.sup.1 ] wherein R.sup.1 and X.sup.1 have the same meaning as those described above, and may be the same or different;
- and
- M.sub.3 and M.sub.4 each represents an anti-fading group of formula (8) and may be the same or different;
- ##STR26## wherein B.sup.7 represents a hydrogen atom, or a substituted or unsubstituted alkyl, alkenyl, aryl, heterocyclic or silyl group having from 1 to 18 carbon atoms;
- and if m is more than 1, the more than one B.sup.7 's may be same or different from each other;
- m represents 1 or 2;
- X.sup.3, X.sup.4 and X.sup.5, which maybe the same or different, each represents --O--, --S-- or .dbd.N--B.sup.8 wherein B.sup.8 is a hydrogen atom or an alkyl or aryl group having up to 18 carbon atoms;
- A.sub.5 and A.sub.6 each represents a linking group may be the same or different;
- and
- R.sup.6 and R.sup.7 each represents a hydrogen atom or an organic residue and maybe the same or different, and
- wherein the monomers containing the anti-fading groups are present in the thermoplastic resin in an amount of 1 mol % or more of the total monomers constituting the thermoplastic resin.
Dependencies are inferred from the claim text.