Aniline derivatives useful as color formers
AssigneeBoehringer Mannheim GmbH
InventorsGunter Frey, Gerd Zimmermann
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AssigneeBoehringer Mannheim GmbH
InventorsGunter Frey, Gerd Zimmermann
Estimating the term…
The present invention is concerned with aniline derivatives of the general formula: ##STR1## wherein R.sub.1 is hydrogen or a lower alkyl or aryl, R.sub.2 is hydrogen or a lower alkyl which can be substituted by hydroxyl, amino carboxyl, lower alkoxycarbonyl, lower alkanoylamide lower alkyl or aryl or by a group of the structure ##STR2## is which R.sub.5 and R.sub.6 have the meanings given hereinafter, R.sub.3 is a hydrogen or halogen atom or a carboxyl group, R.sub.4 and R'.sub.4, which can be the same or different, are hydrogen or halogen, carboxyl or lower alkoxy or lower alkyl radicals which are preferably in the m-position, R.sub.5 is hydrogen or a lower alkyl and R.sub.6 is hydroxyl or a lower alkoxy, lower alkyl or aryl radical; and of the salts thereof with acids and bases useful as a color former in the Trinder reaction for the detection of hydrogen peroxide or hydrogen peroxide-forming systems or peroxidase or peroxidate-acting substances or together with an oxidation agent for the detection of aromatic amines or of systems forming such amines.
An aniline derivative of the formula:
An aniline derivative selected from the group consisting of .alpha.-(N-methyl-anilino)-benzyl-phosphonic acid, (3-chloro-N-methyl-anilino)-methane-phosphonic acid, (3-methyl-N-methyl-anilino)-methane-phosphonic acid, (3-methoxy-N-methyl-anilino)-methane-phosphonic acid, (4-fluoro-N-methyl-anilino)-methane-phosphonic acid, (4-fluoro-3-methyl-N-methyl-anilino)-methane-phosphonic acid, (4-chloro-N-methyl-anilino)-methane-phosphonic acid, (N-ethylanilino)-methane-phosphonic acid, (N-benzylanilino)-methane-phosphonic acid, (N-propylanilino)-methane-phosphonic acid, (N-[2'-carboxyethyl]anilino-methane-phosphonic acid, (N-[2'-ethoxycarbonylethyl]anilino-methane-phosphonic acid, (4-fluoro-N-ethylanilino)-methane-phosphonic acid, (N-phenyl]-anilino)-methane-phosphonic acid, (N-[2-aminoethyl]anilino)-methane-phosphonic acid, 1-(N-methylanilino)-ethane-phosphonic acid, N-hydroxyethyl-anilino-methane-phosphonic acid, ([N-methyl-anilino]-methyl)-methyl-phosphonic acid, (N-methyl-anilino)-methane-phosphonic acid monomethylester, (N-[2-acelamido-ethyl]anilino)-methane-phosphonic acid, and the salt thereof with an acid or a base.
An aniline derivative selected from the group consisting of (3-methyl-N-methyl-anilino)-methane-phosphonic acid, (4-fluoro-N-methyl-anilino)-methane-phosphonic acid, (4-fluoro-3-methyl-N-methyl-anilino)-methane-phosphonic acid, (4-fluoro-N-ethyl-anilino)-methane-phosphonic acid and the salt thereof with an acid or a base.
A compound consisting of (3-methyl-N-methyl-anilino)-methane-phosphonic acid.
A compound consisting of (4-fluoro-N-methyl-anilino)-methane-phosphonic acid.
A compound consisting of (4 -fluoro-3-methyl-N-methyl-anilino)-methane-phosphonic acid.
A compound consisting of (4-fluoro-N-ethyl-anilino)-methane-phosphonic acid.
Dependencies are inferred from the claim text.