Polypropylene resin compositions of high syndiotacticity and preparation process thereof

A polypropylene resin composition of a high syndiotacticity which comprises a substantial homopolymer of propylene, in which the ratio of the intensity of the peak attributable to the syndiotactic pentad bonds to the sum of the intensities of all the peaks attributable to the methyl groups in the spectrum of the methyl groups measured by .sup.13 C-NMR is 0.7 or more, and a copolymer of ethylene and propylene, wherein the molar ratio of ethylene units to propylene units ranges from 15/85 to 85/15, and the weight ratio of said homopolymer to said copolymer ranges from 95/5 to 50/50, said polypropylene resin composition having improved transparency over a syndiotactic homopolymer of propylene and being prepared by first polymerizing propylene substantially singly in the presence of a catalyst capable of forming high syndiotactic polypropylene and then mixing said polypropylene with a copolymer of ethylene and propylene prepared separately from said polypropylene.