Process for isomerizing epoxides to aldehydes
AssigneeArco Chemical Technology, L.P.
InventorMahmoud K. Faraj
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Abstract
A process for isomerizing epoxides to aldehydes is disclosed. The process uses a metal-exchanged zeolite catalyst wherein the zeolite contains an alkali metal and one or more second exchangeable metals from Group IIA, IB, IIB, or IIIB. The catalysts are easily made by combining alkali metal-exchanged zeolites with aqueous solutions that contain halides or nitrates of the second metal. The process is useful for vapor-phase isomerization of propylene oxide to propanal.
Claims15
A process which comprises isomerizing an epoxide having the structure:
- ##STR3## to an aldehyde having the structure:
- ##STR4## in the presence of a metal-exchanged zeolite, wherein the zeolite contains an alkali metal and a second exchangeable metal selected from the group consisting of Group IIA, Group IB, Group IIB, and Group IIIB metals;
- and wherein each of R and R' separately represents hydrogen, a C.sub.1 -C.sub.30 alkyl group, a C.sub.6 -C.sub.30 aryl group, or a C.sub.7 -C.sub.30 aralkyl group.
A process which comprises isomerizing an epoxide having the general structure:
- ##STR5## to an aldehyde having the general structure:
- ##STR6## in the presence of a metal-exchanged zeolite selected from the group consisting of Y-zeolites, X-zeolites, A-zeolites, ZSM-5, and mordenites;
- wherein the zeolite contains an alkali metal and a second exchangeable metal selected from the group consisting of Group IIA, Group IB, Group IIB, and Group IIIB metals;
- and wherein each of R and R' separately represents hydrogen, a C.sub.1 -C.sub.30 alkyl group, a C.sub.6 -C.sub.30 aryl group, or a C.sub.7 -C.sub.30 aralkyl group.
A process which comprises isomerizing propylene oxide to propanal in the vapor phase in the presence of a metal-exchanged Y-zeolite, wherein the Y-zeolite contains an alkali metal and a second metal selected from the group consisting of Group IIA, Group IB, Group IIB, and Group IIIB metals.
The process of claim wherein the process is performed at a temperature within the range of about 100.degree. C. to about 400.degree. C.
Dependencies are inferred from the claim text.