Process for the production of compounds containing aldimine or ketimine groups and the compounds obtained by this process
AssigneeBayer Aktiengesellschaft
InventorsWalter Schafer, Hanns-Peter Muller
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Abstract
The invention relates to a process for the production of organic compounds containing aldimine or ketimine groups by the reaction of compounds containing .beta.-ketoester groups with bis-aldimines or bis-ketimines with elimination of aldehyde or ketone and to the preferred compounds obtained by this process.
Claims1
An organic compound containing aldimine or ketimine groups which corresponds to the formula ##STR5## and is prepared by a process which comprises reacting an organic compound containing .beta.-ketoester groups and corresponding to the formula ##STR6## with 0.75 to 1.0 mole, per mole of ketoester groups, of a bis-aldimine or bis-ketimine corresponding to the formula ##STR7## wherein Q is an n-functional residue obtained by removing the hydroxyl groups from an n-functional polyhydroxyl compound containing primary and/or secondary hydroxyl groups and having a molecular weight of 62 to 15,000,
- R.sub.1 is hydrogen or is attached to R.sub.2 by a C--C bond and with R.sub.2 forms a tri- or tetramethylene group,
- R.sub.2 is a methyl or ethyl group or is attached to R.sub.1 by a C--C bond and with R.sub.1 forms a tri- or tetramethylene group,
- R.sub.3 is a C.sub.1-9 alkyl radical or, together with the carbon atom and the substituent R.sub.4, forms a cycloaliphatic ring containing 5 or 6 ring members,
- R.sub.4 is a C.sub.1-9 alkyl radical or, together with the carbon atom and the substituent R.sub.3, forms a cycloaliphatic ring containing 5 or 6 ring members,
- R.sub.5 is a (cyclo)aliphatic C.sub.2-15 hydrocarbon radical and
- n is a number from 2 to 15,
- at a temperature of 0.degree. to 80.degree. C. in the presence of a catalytic quantity of water with elimination of aldehyde or ketone in a quantity equivalent to the quantity of ketoester groups.
Dependencies are inferred from the claim text.