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US 5,312,940 AGranted
Ruthenium and osmium metal carbene complexes for olefin metathesis polymerization
AssigneeCalifornia Institute of Technology
InventorsRobert H. Grubbs, Lynda K. Johnson, Sonbinh T. Nguyen
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Abstract
Processes for the synthesis of several new carbene compounds of ruthenium and osmium are provided. These novel complexes function as stable, well-defined catalysts for the metathesis polymerization of cyclic olefins.
Claims7
A compound of the formula ##STR35## wherein:
- M is Os or Ru;
- R and R.sup.1 are independently selected from hydrogen;
- C.sub.2 -C.sub.20 alkenyl, C.sub.2 -C.sub.20 alkynyl, C.sub.1 -C.sub.20 alkyl, aryl, C.sub.1 -C.sub.20 carboxylate, C.sub.1 -C.sub.20 alkoxy, C.sub.2 -C.sub.20 alkenyloxy, C.sub.2 -C.sub.20 alkynyloxy, aryloxy, C.sub.2 -C.sub.20 alkoxycarbonyl, C.sub.1 -C.sub.20 alkylthio, C.sub.1 -C.sub.20 alkylsulfonyl or C.sub.1 -C.sub.20 alkylsulfinyl;
- each optionally substituted with C.sub.1 -C.sub.5 alkyl, halogen, C.sub.1 -C.sub.5 alkoxy or with a phenyl group optionally substituted with halogen, C.sub.1 -C.sub.5 alkyl or C.sub.1 -C.sub.5 alkoxy;
- X and X.sup.1 are independently selected from any anionic ligand;
- L and L.sup.1 are independently selected from any neutral electron donor, and
- wherein any 2, or 3 of X, X.sup.1, L, and L.sup.1 are optionally bonded together to form a chelating multidentate ligand.
4 more elements
A compound selected from the group consisting ##STR36##
Dependencies are inferred from the claim text.