A photosensitive material for electrophotography which comprises a conductive support, and a charge transport layer and a charge generation layer formed on the conductive support in this order, said charge generation layer having a thickness of from 10 to 50 micrometers and being formed from a dispersion which is obtained by mixing X-type and/or .tau.-type metal-free phthalocyanine and a resin binder in a solvent, which is capable of dissolving at least a part of X-type and/or .tau.-type metal-free phthalocyanine, to such an extent that a ratio between X-ray diffraction peak intensities at about 7.5.degree. and at about 9.1.degree. is in the range of 1:1 to 0.1:1.