Fluoroalkene/hydrofluorocarbon telomers and their synthesis
AssigneeE. I. Du Pont de Nemours and Company
InventorRichard E. Peavy
Life of this patent
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Abstract
The invention relates to fluorotelomers, their synthesis by free radical-initiated telomerization of fluoroalkenes (e.g. TFE) in which hydrofluorocarbons (HFC's) are used both as telogens and as solvents, and dispersions of the fluorotelomers in HFC's. The fluorotelomers are normally solid, essentially non-distillable and highly crystalline, and their dispersions exhibit excellent lubricant properties and stability under normal usage and have a negligible impact on the environment compared to conventional telomer dispersions.
Claims12
A process for preparing a fluorotelomer which consists essentially in reacting tetrafluoroethylene or hexafluoropropylene with a hydrofluorocarbon telogen in solution in said hydrofluorocarbon in the presence of a free radical initiator at a temperature in excess of 110.degree. C. and up to 200.degree. C., wherein said hydrofluorocarbon:
- consists essentially of an acyclic organic compound having a boiling point at atmospheric pressure between 25.degree. C. and 150.degree. C. and containing 2 to 8 carbon atoms, fluorine, at least one hydrogen, with or without one or more ether oxygen atoms, in which there are at least
- as many fluorine atoms as there are hydrogen atoms;
- provided that said organic compound contains neither any
- (1) alkyl group which is bonded to a perfluorinated group;
- nor
- (2) adjacent --CH.sub.2 -- groups, except when said adjacent --CH.sub.2 -- groups are part of a cyclic organic compound,
- and recovering a fluorotelomer having a number average molecular weight between 1800 and 75,000.
A process for preparing a fluorotelomer which consists essentially in reacting tetrafluoroethylene with a hydrofluorocarbon telogen in solution in said hydrofluorocarbon in the presence of a free radical initiator at a temperature in the range between 120.degree. and 160.degree. C., wherein said hydrofluorocarbon:
- consists essentially of an acryclic organic compound having a boiling point at atmospheric pressure between 25.degree. C. and 150.degree. C. and containing 2 to 8 carbon atoms, fluorine, at least one hydrogen, with or without one or more ether oxygen atoms, in which there are at least as many fluorine atoms as there are hydrogen atoms;
- provided that said organic compound contains neither any
- (1) alkyl group which is bonded to a perfluorinated group;
- nor
- (2) adjacent --CH.sub.2 -- groups, except when said adjacent --CH.sub.2 -- groups are part of a cyclic organic compound, and recovering a fluorotelomer having a number average molecular weight between 1800 and 75,000.
Dependencies are inferred from the claim text.