Organopolysiloxane and method for the preparation thereof
AssigneeDow Corning Toray Silicone Co., Ltd.
InventorYoshitsugu Morita
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Abstract
An MQ organopolysiloxane compatible with organic plastics, has an epoxy-containing organic group, and has the following general formula ##STR1## R.sup.1 represents monovalent hydrocarbon groups, R.sup.2 represents the hydrogen atom and monovalent hydrocarbon groups, R.sup.3 represents epoxy-containing organic groups and alkoxysilylalkyl groups, a is 0 or a positive number, b and c are positive numbers, a/c has a value of 0 to 4, b/c has a value of 0.05 to 4, and (a+b)/c has a value of 0.2 to 4. Also, a method for the preparation of this organopolysiloxane comprises an addition reaction of an Si-H containing organopolysiloxane with an epoxy-containing compound in the presence of a hydrosilylation catalyst.
Claims7
A method for producing an organopolysiloxane having an epoxy-containing organic group comprising reacting in the presence of
- (A) a hydrosilylation-reaction catalyst, with
- (B) an SiH-containing organopolysiloxane with the general formula ##STR14## R.sup.1 is a non-alkenyl monovalent hydrocarbon group, d is 0 or a positive number, e and f are positive numbers, d/f has a value of 0 to 4, e/f has a value of 0.05 to 4, and (d+e)/f has a value of 0.2 to 4,
- (C) an aliphatically unsaturated epoxy-containing organic compound, and optionally
- (D) an alkoxysilylalkene, where the moles of aliphatic unsaturation in (C) and (D) is less than the moles of silicon-bonded hydrogen atoms in (B).
A method for producing an organopolysiloxane having an epoxy-containing organic group comprising reacting in the presence of
- (A) a hydrosilylation-reaction catalyst, with
- (B) an SiH-containing organopolysiloxane with the general formula ##STR16## R.sup.1 is a non-alkenyl monovalent hydrocarbon group, d is 0 or a positive number, e and f are positive numbers, d/f has a value of 0 to 4, e/f has a value of 0.05 to 4, and (d+e)/f has a value of 0.2 to 4,
- (C) an aliphatically unsaturated epoxy-containing organic compound, and optionally
- (D) an alkoxysilylalkene, where (A) is first mixed with (B), (C) is then added and (D) is subsequently added, and where the moles of aliphatic unsaturation in (C) and (D) is equal to or more than the moles of silicon-bonded hydrogen atoms in (B).
A method for producing an organopolysiloxane having an epoxy-containing organic group comprising reacting in the presence of
- (A) a hydrosilylation-reaction catalyst and an organic solvent, with
- (B) an SiH-containing organopolysiloxane with the general formula ##STR17## R.sup.1 is a non-alkenyl monovalent hydrocarbon group, d is 0 or a positive number, e and f are positive numbers, d/f has a value of 0 to 4, e/f has a value of 0.05 to 4, and (d+e)/f has a value of 0.2 to 4,
- (C) an aliphatically unsaturated epoxy-containing organic compound, and optionally
- (D) an alkoxysilylalkene where the moles of aliphatic unsaturation in (C) is less than the moles of silicon-bonded hydrogen atoms in (B).
Dependencies are inferred from the claim text.