Transparent two-part acrylic adhesive composition and the method of use thereof
AssigneeNational Starch and Chemical Investment Holding Corporation
InventorsMartin M. Skoultchi, Dilip K. Ray-Chaudhuri
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Abstract
In a two-part adhesive composition wherein one-part comprises a polymerizable acrylic monomer and an organoboron amine complex and the second-part contains an organic acid destabilizer and optional acrylic polymer, the improvement wherein a transparent or clear bond is provided in the cured adhesive composition by having about 45% or more by weight of the total acrylic monomer in the composition comprising selected phenyl containing acrylic compounds.
Claims12
In a curable two-part adhesive composition wherein one part comprises a polymerizable acrylic monomer and an effective amount of a stabilized organoboron amine complex initiator of the formula:
- ##STR6## where R, R.sub.1 and R.sub.2 are alkyl of 1 to 10 carbon atoms or phenyl, R.sub.3 and R.sub.4 are hydrogen or alkyl of 1 to 10 carbon atoms;
- or ##STR7## where R.sub.5 and R.sub.6 are hydrogen or alkyl of 1 to 10 carbon atoms, m is 2 to 10 and n is 1 to 6;
- and the second part contains an effective destabilizing amount of an organic acid activator having the formula:
- R--COOH
- where R is H, alkyl or alkenyl of 1 to 8 carbon atoms or aryl of 6 to 10 carbon atoms, the improved composition providing a transparent or clear bond in the cured adhesive wherein the acrylic monomer comprises about 45% or more by weight, based on the total weight of acrylic monomer in the composition, of a monomer selected from the group consisting of benzyl acrylate or methacrylate, 2-phenoxyethyl acrylate or methacrylate, phenyl acrylate or methacrylate and 2-phenylethyl acrylate or methacrylate.
Dependencies are inferred from the claim text.