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US 5,310,793 AGranted
Mixtures of polyalkylene terephthalates, new polycarbonates and/or polyester-carbonates and elastomers
AssigneeBayer Aktiengesellschaft
InventorsDieter Freitag, Karsten-Josef Idel, Gerd Fengler, Ulrich Grigo, Jurgen Kirsch, Uwe Westeppe
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Abstract
The mixtures according to the present invention of polyalkylene terephthalates, certain new polycarbonates and/or polyester-carbonates and elastomers have a particularly favourable low temperature strength/heat distortion point relationship compared with conventional moulding compositions containing known polycarbonates. The mixtures are used for the production of, in particular, shaped articles.
Claims3
A molding composition comprising
- (A) from 20 to 80 wt. % of a polyalkylene terephthalate;
- (B) from 1 to 50 wt. % of a thermoplastic aromatic polycarbonate and/or polyester-carbonate based on a mixture of aromatic diphenols containing
- (1) from 20 to 100 mole percent, based on the total of diphenols (B)(1) and (B)(2), of 1,1-bis(4-hydroxyphenyl)-3,3,5-trimethylcyclohexane corresponding to the formula ##STR5## (2) 0 to 80 mole percent, based on the total of diphenols (B)(1) and (B)(2), of 2,2-bis(4-hydroxyphenyl)propane, 2,2-bis(3,5-dimethyl-4-hydroxyphenyl)propane, 2,2-bis(3,5-dichloro-4-hydroxyphenyl)propane, 2,2-bis(3,5-dibromo-4-hydroxyphenyl)propane, or 1,1-bis(4-hydroxyphenyl)cyclohexane;
- and
- (C) from 1 to 30 wt. % of an elastomer, wherein said elastomer is a grafted polymer having an average particle diameter d.sub.50 of from 0.2 to 0.6 obtained by grafting
- (1) from 10 to 40 wt. %, based on the grafted polymer, of
- (i) at least one (meth)acrylic acid ester and/or
- (ii) a mixture comprising from 10 to 35 wt. %, based on the mixture, of acrylonitrile and from 65 to 90 wt. %, based on the mixture, of styrene,
- onto
- (2) from 60 to 90 wt. %, based on the grafted polymer, of a butadiene polymer having at least 70 wt. %, based on the butadiene polymer, of butadiene radicals as the grafting base, wherein the gel content of the grafting base is at least 70% (as measured in toluene) and the degree of grafting G is from 0.15 to 0.5 .mu.m,
- with the proviso that components (A) to (C) total 100 wt. %, based on the total amount of components (A) to (C).
8 more elements
Dependencies are inferred from the claim text.