Catalyst system for the polymerization of olefins
AssigneeFina Technology, Inc.
InventorsEdwar S. Shamshoum, David J. Rauscher
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AssigneeFina Technology, Inc.
InventorsEdwar S. Shamshoum, David J. Rauscher
Estimating the term…
The present invention provides a catalyst system that exhibits unprecedented catalyst efficiencies and control of desired properties in the polymer product. The catalyst system includes a new generation titanium catalyst in combination with an electron donor described by the formula: ##STR1## wherein R.sub.1 is an alkyl or cycloalkyl group containing a primary or secondary carbon atom attached to the silicon atom; R.sub.2 and R.sub.3 are alkyl or aryl groups; and R.sub.4 is an alkyl or cycloalkyl group with a primary or secondary carbon atom attached to the silicon atom. The system has a catalyst efficiency of over 30 kg/g-cat.h as the Si/Ti mole ratio varies from 4-20 in the system. The system easily achieves efficiencies over 30 kg/g-cat.h. The system also exhibits good control over the xylene solubles of the polymer products.
In a system for the polymerization and copolymerization of olefins, the combination comprising:
A catalyst system for the polymerization and copolymerization of olefins, said system comprising:
Dependencies are inferred from the claim text.