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US 5,308,537 AGranted
Mesogenic compounds
AssigneeMerck Patent GmbH
InventorsDavid Coates, Simon Greenfield, Ian C. Sage, Volker Reiffenrath, Bernhard Rieger
Life of this patent
Estimating the term…
Abstract
Mesogenic compounds with a .omega.-CF.sub.3 -alkyl, .omega.-CF.sub.3 -alkenyl or .omega.-CF.sub.3 -alkinyl terminal group of formula I ##STR1## with the meaning of R, Z, Q, ##STR2## m, n and o being indicated in claim 1.
Claims2
In a nematic liquid crystalline medium, comprising at least two liquid crystalline compounds, the improvement wherein at least one compound is a mesogenic compound with a .omega.-CF.sub.3 -alkenyl or a .omega.-CF.sub.3 -alkynyl terminal group of formula I
- wherein
- R is an unsubstituted, a mono cyano or trifluoromethyl substituted or a mono-, oligo- or polyhalogeno-substituted alkyl or alkenyl residue having 1 to 15 carbon atoms, or such a residue wherein one or more CH.sub.2 groups are each independently replaced by --O--, --CO--, --CO--O--, --O--CO-- or --O--CO--O with the proviso that oxygen atoms are not directly attached to each other,
- the rings A and B independently are
- (a) a trans-1,4-cyclohexylene group, wherein one or more two non-adjacent CH.sub.2 groups may also be replaced by at least one of --O-- or --S-- or one or two CH groups may be replaced by N,
- (b) a 1,4-phenylene group, wherein one or two CH groups may be replaced by N,
- (c) 1,4-bicyclo-(2,2,2-octylene, 1,4-cyclohexenylene, napthalin-2,6-diyl or 1,3-cyclo-butylene,
- groups (a) and (b) being optionally substituted by one or more of halogen, cyano or methyl,
- Z is independently from each other --CO--O, --O--CO--, --CH.sub.2 CH.sub.2 --, --CH.sub.2 O--, --OCH.sub.3 --, --C.tbd.C, --CH.dbd.N--, --N.dbd.CH-- or a single bond,
- Q is --C.tbd.C or --CH.dbd.CH--,
- m is 1, 2 or 3 and
- n an o are independently from each other zero or integers from 1 to 10.
8 more elements
Dependencies are inferred from the claim text.