Electro-optical system containing a compensating film
AssigneeMerck Patent GmbH
InventorsBernhard Scheuble, Bernhard Rieger, Dieter Dorsch
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Abstract
The invention relates to electro-optical systems containing an addressable liquid-crystal layer and a device for compensating for the optical path difference d.multidot..DELTA.n of the addressable liquid-crystal layers, the compensating device being based on a liquid-crystalline polymer.
Claims27
In an electro-optical system comprising at least one addressable liquid-crystal layer and means for compensating for the optical path difference d.multidot..DELTA.n of said at least one addressable liquid-crystal layer, the improvement wherein said compensating means comprises:
- a liquid-crystalline side-chain polymer containing monomer units of formula I:
- ##STR18## wherein P is a polymer main-chain unit,
- Sp is a bivalent spacer group connecting radical B to polymer main chain, and
- B is an organic "rod-like" radical containing at least two six-membered groups, a "disc-like" radical or a "board-like" radical;
- or
- a liquid crystal elastomer containing 3-dimensionally crosslinked monomer units of formula II:
- ##STR19## wherein P, Sp and B are as defined above, and
- V is a crosslinking unit linking together two adjacent polymer chains.
A process for producing a device for compensating for the optical path difference d.multidot..DELTA.n of an addressable liquid-crystal layer, wherein said device is based on a liquid-crystalline polymer, comprising:
- axially orienting a liquid-crystal polymer, by applying an electrical or magnetic field or by mechanical stress, above the glass transition temperature, and freezing-in this orientation by cooling said liquid-crystalline polymer to a temperature below said glass transition temperature, said liquid crystal polymer being a side-chain polymer containing monomer units of formula I:
- ##STR20## wherein P is a polymer main-chain unit,
- Sp is a bivalent spacer group connecting radical B to polymer main chain, and
- B is an organic "rod-like" radical containing at least two six-membered groups, a "disc-like" radical or a "board-like" radical;
- or
- a liquid crystal elastomer containing 3-dimensionally crosslinked monomer units of formula II:
- ##STR21## wherein P, Sp and B are as defined above, and
- V is a crosslinking unit linking together two adjacent polymer chains.
In a method of compensating for the optical path difference of an addressable liquid-crystal layer, the improvement wherein a liquid-crystalline polymer is used as a means for compensating said optical path difference and said liquid-crystalline polymer is a side-chain polymer containing monomer units of formula I:
- ##STR22## wherein P is a polymer main-chain unit,
- Sp is a bivalent spacer group connecting radical B to polymer main chain, and
- B is an organic "rod-like" radical containing at least two six-membered groups, a "disc-like" radical or a "board-like" radical;
- or
- a liquid crystal elastomer containing 3-dimensionally crosslinked monomer units of formula II:
- ##STR23## wherein P, Sp and B are as defined above, and
- V is a crosslinking unit linking together two adjacent polymer chains.
Dependencies are inferred from the claim text.