Heterocyclic compounds useful as additives for lubricant and fuel compositions
AssigneeThe Lubrizol Corporation
InventorsJoseph W. Pialet, Paul E. Adams
Life of this patent
Estimating the term…
Abstract
Various heterocyclic compounds have been discovered that impart improved fuel economy and friction modification to lubricant and fuel compositions. These heterocyclic compounds of the invention preferably contain nitrogen and may be further reacted with hydrocarbyl carboxylic acid acylating reactants or hydrocarbyl phenolic reactants to give higher molecular materials. These higher molecular weight materials have higher oil-solubility and impart dispersancy properties to lubricant and fuel compositions.
Claims9
A composition comprising at least one compound represented by the formula ##STR13## wherein:
- Z is S, NR, ##STR14## T is NH.sub.2, NHR, SH, OH or their tautomers, hydrocarbyl acyl or hydrocarbyl phenolate;
- Y is, ##STR15## COOH or CH.sub.2 NH.sub.2 ;
- each X is independently H, COOH, NH.sub.2, CONH.sub.2, NHNH.sub.2, OR, COR, NHR, OH, SH or CN:
- p is zero to 2;
- e is zero to 2;
- e+p is 2 to about 4;
- A is O or S;
- and
- R is H, alkyl, alkenyl, hydrocarbyl acyl, hydrocarbyl phenolate or --(CH.sub.2).sub.m Q, wherein m is 1 to about 12 and Q is O-alkyl or N-alkyl.
A composition comprising at least one compound represented by the formula ##STR16## wherein:
- X is H, COOH, NH.sub.2 or CONH.sub.2 ;
- ##STR17## CO.sub.2 H or CH.sub.2 NH.sub.2 ;
- A is O or S;
- and R is H, alkyl, alkenyl, hydrocarbyl acryl, hydrocarbyl phenolate or --(CH.sub.2).sub.m Q wherein m is 1 to about 12 and Q is O-alkyl or N-alkyl.
A concentrate comprising at least one substantially inert normally liquid organic diluent or solvent, and from about 1% to about 99% by weight of at least one compound represented by the formula ##STR18## wherein:
- Z is S, NR, ##STR19## T is NH.sub.2, NHR, SH, OH or their tautomers, hydrocarbyl acyl or hydrocarbyl phenolate;
- Y is ##STR20## COOH or CH.sub.2 NH.sub.2 ;
- each X is independently H, COOH, NH.sub.2, CONH.sub.2, NHNH.sub.2, OR, COR, NHR, OH, SH or CN;
- p is zero to 2;
- e is zero to 2;
- e+p is 2 to about 4;
- A is O or S;
- and
- R is H, alkyl, alkenyl, hydrocarbyl acyl, hydrocarbyl phenolate or --(CH.sub.2).sub.m Q, wherein m is 1 to about 12 and Q is O-alkyl or N-alkyl.
A concentrate comprising at least one substantially inert normally liquid organic diluent or solvent, and from about 1% to about 99% by weight of at least one compound represented by the formula ##STR21## wherein:
- X is H, COOH, NH.sub.2 or CONH.sub.2 ;
- Y is ##STR22## CO.sub.2 H or CH.sub.2 NH.sub.2 ;
- A is O or S;
- and R is H, alkyl, alkenyl, hydrocarbyl acyl, hydrocarbyl phenolate or --(CH.sub.2).sub.m Q wherein is 1 to about 12 and Q is O-alkyl or N-alkyl.
A lubricating composition comprising a major amount of an oil of lubricating viscosity and a minor fuel-economy improving, detergent, antioxidant, rust-inhibiting or antiwear amount of at least one compound represented by the formula ##STR23## wherein:
- Z is S, NR, ##STR24## T is NH.sub.2, NHR, SH, OH or their tautomers, hydrocarbyl acyl or hydrocarbyl phenolate;
- Y is ##STR25## COOH or CH.sub.2 NH.sub.2 ;
- each X is independently H, COOH, NH.sub.2, CONH.sub.2, NHNH.sub.2, OR, COR, NHR, OH, SH or CN;
- p is zero to 2;
- e is zero to 2;
- e+p is 2 to about 4;
- A is O or S;
- and
- R is H, alkyl, alkenyl, hydrocarbyl acyl, hydrocarbyl phenolate or --(CH.sub.2).sub.m Q, wherein m is 1 to about 12 and Q is O-alkyl or N-alkyl.
A lubricating composition comprising a major amount of an oil of lubricating viscosity and a minor fuel-economy improving, detergent, antioxidant, rust-inhibiting or antiwear amount of at least one compound represented by the formula ##STR26## wherein:
- X is H, COOH, NH.sub.2 or CONH.sub.2 ;
- ##STR27## CO.sub.2 H or CH.sub.2 NH.sub.2 ;
- A is O or S;
- and R is H, alkyl, alkenyl, hydrocarbyl acyl, hydrocarbyl phenolate or --(CH.sub.2).sub.m Q wherein m is 1 to about 12 and Q is O-alkyl or N-alkyl.
A composition comprising at least one compound represented by the formula ##STR28## wherein R is H, alkyl, alkenyl, hydrocarbyl acyl, hydrocarbyl phenolate or --(CH.sub.2).sub.m Q, wherein m is 1 to about 12 and Q is O-alkyl or N-alkyl.
A concentrate comprising at least one substantially inert normally liquid organic diluent or solvent, and from about 1% to about 99% by weight of at least one compound represented by the formula ##STR29## wherein R is H, alkyl, alkenyl, hydrocarbyl acyl, hydrocarbyl phenolate or --(CH.sub.2).sub.m Q, wherein m is 1 to about 12 and Q is O-alkyl or N-alkyl.
A lubricating composition comprising a major amount of an oil of lubricating viscosity and a minor amount of at least one compound represented by the formula ##STR30## wherein R is H, alkyl, alkenyl, hydrocarbyl acyl, hydrocarbyl phenolate or --(CH.sub.2).sub.m Q, wherein m is 1 to about 12 O is O-alkyl or N-alkyl.
Dependencies are inferred from the claim text.