Pyridine compounds which have useful insecticidal utility
AssigneeNippon Soda Co., Ltd.
InventorsKeiichi Ishimitsu, Junji Suzuki, Haruhito Ohishi, Tomio Yamada, Renpei Hatano, Nobuo Takakusha, Jun Mitsui
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AssigneeNippon Soda Co., Ltd.
InventorsKeiichi Ishimitsu, Junji Suzuki, Haruhito Ohishi, Tomio Yamada, Renpei Hatano, Nobuo Takakusha, Jun Mitsui
Estimating the term…
The present invention relates to a compound having the formula below which has an excellent inseciticidal activity: ##STR1## wherein R.sub.1 represents an optionally substituted 5-6 membered aromatic hetero ring containing nitrogen atom, except a non-substituted 2-pyridyl; x represents an optionally substituted C.sub.1-3 alkylene R.sub.2 represents a hydrogen, a carbamoyl, a mono or di C.sub.1-5 alkyl carbamoyl, a thiocarbamoyl, a mono or di C.sub.1-5 alkylthiocarbamoyl, a sulfamoyl, a mono or di C.sub.1-5 alkylsulfamoyl, an optionally substituted C.sub.1-5 alkyl, an optionally substituted C.sub.2-5 alkenyl, an optionally substituted C.sub.2-5 alkynyl, an optionally substituted C.sub.3-8 cycloalkyl, an optionally substituted C.sub.3-8 cycloalkenyl, an optionally substituted aryl or --Y--R.sub.5 ; Y represents O, S(O).sub.n, CO, CS or CO.sub.2 ; n represents 0, 1 or 2; R.sub.5 represents a hydrogen, an optionally substituted C.sub.1-5 alkyl, an optionally substituted C.sub.2-5 alkenyl, an optionally substituted C.sub.2-5 alkynyl, an optionally substituted C.sub.3-8 cycloalkyl, an optionally substituted C.sub.3-8 cycloalkenyl or an optionally substituted aryl; R.sub.3 represents a hydrogen, an optionally substituted C.sub.1-5 alkyl, an optionally substituted C.sub.2-5 alkenyl, an optionally substituted C.sub.2-5 alkynyl, an optionally substituted C.sub.3-8 cycloalkyl or an optionally substituted C.sub.3-8 cycloalkenyl; R.sub.4 represents a cyano or a nitro; and Z represents CH or N; or its salt.
An insecticidal compound of the formula ##STR269## wherein A completes a 5 or 6 membered aromatic ring having one heteroatomic ring member comprising nitrogen, provided, however, that the ring is not unsubstituted 2-pyridyl;
N-cyano-N'-(2-chloro-5-pyridylmethyl)-N'-methylacetamidine.
2-(2-chloro-5-pyridylmethylamino)-1-nitro-1-butene.
N-cyano-N'-(2-chloro-5-pyridylmethyl)-N'-ethylacetamidine.
N-(2-chloro-5-pyridylmethyl)-N-methyl-N'-nitroacetamidine.
Dependencies are inferred from the claim text.