Modified cellulose ethers and the use thereof in dispersion paints
AssigneeHoechst Aktiengesellschaft
InventorsChristoph Meister, Reinhard Donges, Walter Schermann, Walter Schrattenholz
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Abstract
The invention relates to water-soluble cellulose ethers, containing at least one fluorine-free radical attached via an ether link and selected from the group hydroxyethyl, hydroxypropyl, methyl, ethyl and carboxymethyl, and a hydrophobic substituent which comprises one fluorine-containing alkyl radical of 3 to 24, in particular 5 to 18, carbon atoms, the fluorine content being 0.05 to 5, in particular 0.1 to 1% by weight, based on the dry weight of the cellulose ether.
Claims16
A water-soluble cellulose ether containing at least one fluorine-free radical attached via an ether link and selected from the group hydroxyethyl, hydroxypropyl, methyl, ethyl and carboxymethyl, and a hydrophobic substituent which comprises a fluorine-containing alkyl radical containing 3 to 24 carbon atoms, the fluorine content being 0.05 to 5, by weight, based on the dry weight of the cellulose ether wherein the hydrophobic substituent attached to the cellulose ether has one of the formulae selected from the group consisting of
- (a) R--CH(OH)--CH.sub.2 --O--cellulose ether
- (b) R.sup.1 --CHF--CFR--O--cellulose ether
- (c) R--CHF--CFR.sup.1 --O--cellulose ether
- (d) R--O--cellulose ether
- (e) R--O--CH.sub.2 --CH(OH)--CH.sub.2 --O--cellulose ether
- (f) Y--CHX--CX.sub.2 --O--cellulose ether
- (g) Y--CHX--CXR.sup.2 --O--cellulose ether
- (j) HCRR.sup.2 --CO--O--cellulose ether
- (l) R--NH--CO--O--cellulose ether
- in which R and R.sup.1 are each a (C.sub.1 -C.sub.22)alkyl radical and R.sup.2 is either H or a (C.sub.1 -C.sub.22)alkyl radical, the total number of the carbon atoms of the alkyl groups of the formulae (b), (c) and (j) being 3 to 24,
- X is fluorine and/or hydrogen and
- Y is --CN or --CO.sub.2 R.sup.3, R.sup.3 being a (C.sub.1 -C.sub.22)alkyl radical, and in the formulae (a) to (g) at least 3 carbon atoms, in the formula (j) and (l) at least 2 carbon atoms, of the substituents are linked with fluorine atoms.
The method of thickening a dispersion paint comprising the step of incorporating in a dispersion paint a cellulose derivative consisting of water-soluble cellulose ether containing at least one fluorine-free radical attached via an ether link and selected from the group hydroxymethyl, and a hydrophobic substituent which comprises a fluorine-containing alkyl radical containing 3 to 24, the fluorine content being 0.05 to 5% by weight, based on the dry weight of the cellulose ether.
Dependencies are inferred from the claim text.