Process for obtaining modified polyethylene terephthalate pilling-free fibres originating from the polymer thus modified
AssigneeRhone-Poulenc Fibres
InventorsDenis Jehl, Bernard Millaud, Jean Staron
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AssigneeRhone-Poulenc Fibres
InventorsDenis Jehl, Bernard Millaud, Jean Staron
Estimating the term…
The present invention relates to a process for obtaining continuously polyethylene terephthalate modified by --SiO-- groups in a proportion of 300-700 ppm of Si during the direct esterification reaction between terephthalic acid and ethylene glycol, followed by polycondensation in a known manner by introducing methoxyethyl silicate or propyl silicate at a time when the prepolymer has a weight-average molecular mass of between 9,000 and 16,000, a polydispersity index of between 1.5 and 2, and when it is at a temperature of between 260.degree. and 290.degree. C. and at a pressure of between 1.5 and 2.5 bars, the silicate/prepolymer reaction time being at least 5 minutes. The present invention also relates to pilling-free fibres originating from the modified polyethylene terephthalate and to a process for obtaining them.
A pilling-free fiber capable of being employed in a mixture with at least one cotton fiber for weaving applications, based on polyethylene terephthalate modified with --SiO-- groups bonded chemically to the macromolecular chains in an amount of 300 to 700 ppm of silicon and having:
Dependencies are inferred from the claim text.