An electric arc reactor including, an upstream electrode and a downstream electrode which are connectable to a power source such as to enable an arc to be generated between them, a feed material passage extending in a substantially straight path through said electrodes and being connectable to a source of feed material at an injection end thereof, an upstream portion of said feed passage extending through said upstream electrode, an electrode gap formed between adjacent inner ends of said electrodes which are spaced apart in the direction of said passage, said injection end being at an outer end of said upstream passage portion remote from said gap, rotation inducing means whereby said arc is caused to rotate about the axis of said passage to create a hollow arc column through which feed material can pass, and manifold means arranged to direct a flow of gas into said gap so that a component of said flow is in a direction towards said injection end and said gas enters said upstream passage portion at the inner end of said upstream electrode to flow along an inner surface of said upstream electrode, whereby in use the flow along said inner surface is counter to the flow of said feed material and a stagnation zone is thereby created at said inner surface, and the upstream root of said arc is confined to attachment to said inner surface at said stagnation zone.