Indirect cerium medicated electrosynthesis
AssigneeHydro-Quebec
InventorStephen Harrison
Life of this patent
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Abstract
An integrated process for oxidizing aromatic and alkyl aromatic compounds to form carbonyl containing reaction products comprising the reaction of quadravalent cerium with a reactant stream containing an aromatic or alkyl aromatic compound and using a high degree of mixing, followed by the electrolytic regeneration of the reduced cerium ion in a cell under near turbulent or turbulent flow conditions at high solution velocities relative to the anode. The preferred cell structure for accomplishing the electrolysis utilizes an turbulence promoting anode arrangement which allows for the anolyte to flow past the anode under the conditions mentioned, and a reduced area cathode whereby the anode and cathode compartments need not be separated by an ion exchange membrane.
Claims9
An electrochemical cell comprising an anode and a cathode, wherein said anode includes:
- (a) an electrically conductive flat plate having an edge and two side surfaces, and a generally planar electrically conductive sheet of expanded mesh positioned parallel with and electrically contacting one of said side surfaces, and
- (b) means for flowing an electrolyte containing cerium.sup.III over said anode at near turbulent or turbulent flow rates.
An electrochemical cell comprising an anode and a cathode, wherein said anode includes:
- (a) an electrically conductive flat plate having an edge and two side surfaces, and a generally planar electrically conductive sheet of expanded mesh positioned parallel with and electrically contacting one of said side surfaces, and
- (b) means for flowing an electrolyte containing cerium.sup.III over said anode at near turbulent or turbulent flow rates;
- wherein said flat plate and said mesh are platinized titanium.
An electrochemical cell for oxidizing cerium.sup.III to cerium.sup.IV comprising:
- (a) a cell having an anode compartment and a cathode comprising:
- (b) an anode positioned within said anode compartment, said anode comprising a conductive flat plate having an edge and two side surfaces, and a generally planar conductive expanded mesh sheet positioned parallel with and electrically contacting one of said side surfaces, and means for connecting said anode to a power source;
- (c) means for flowing an electrolyte solution containing cerium.sup.III through at least said anode compartment and over said anode at near turbulent or turbulent flow rates;
- and
- (d) a cathode positioned within said cathode compartment and means for connecting said cathode to a power source.
An electrochemical cell for oxidizing cerium.sup.III to cerium.sup.IV comprising:
- (a) a cell having an anode compartment and a cathode compartment;
- (b) an anode positioned within said anode compartment, said anode comprising a conductive flat plate having an edge and two side surfaces, and a generally planar conductive expanded mesh sheet positioned parallel with and electrically contacting one of said side surfaces, and means for connecting said anode to a power source;
- (c) means for flowing an electrolyte solution containing cerium.sup.III through at least said anode compartment and over said anode at near turbulent or turbulent flow rates;
- and
- (d) a cathode positioned within said cathode compartment and means for connecting said cathode to a power source;
- wherein said cell has no membrane separator and said cathode has a surface area of one-third or less than a total surface area of said anode.
A process for oxidizing cerium III to cerium IV in an electrochemical cell at an anode including an electrically conductive planar sheet having an edge and two side surfaces, and a generally planar sheet of electrically conductive mesh positioned parallel with and electrically contacting one of said side surfaces, said process comprising the steps of flowing an electrolyte stream containing cerium III ions over said anode at near turbulent or turbulent flow rates.
Dependencies are inferred from the claim text.