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US 5,295,086 AGranted
Method of producing noise free frequency spectrum signals
AssigneeJEOL Ltd.
InventorsMineo Kumazawa, Yuichi Imanishi, Toshio Matsuura
Life of this patent
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Abstract
Method of making a spectral analysis of a free induction decay signal picked up by a pulse nuclear magnetic resonance spectrometer. The sine component and the cosine component of the signal which are .pi./2 out-of-phase are sampled. The resulting data is analyzed by the Sompi method extended to the complex domain. The Sompi method utilizes an autoregressive model.
Claims10
A spectroscopy method comprising:
- (a) producing an output signal being the output of a spectrometer, said signal comprising the summation of signals of multiple frequencies;
- (b) digitizing and sampling the two components of the output signal which are .pi./2 radians out-of-phase at spaced time intervals to produce time series data;
- (c) converting the time series data to a frequency spectrum while enhancing the data by applying the Sompi method utilizing an autoregressive model to the data values, the Sompi method being extended to the complex time domain;
- and
- (d) displaying a substantially noise free frequency spectrum.
2 more elements
A spectroscopy method comprising:
- (a) producing an output signal being the output of a spectrometer, said signal comprising the summation of signals of multiple frequencies;
- (b) digitizing and sampling the two components of the output signal which are .pi./2 radians out-of-phase at spaced time intervals to produce time series data;
- (c) converting the time series data to a frequency spectrum by finding frequencies and attentuation constants of wave elements by use of an autoregressive model comprising:
- i) applying a fitting method to the time series data using the frequencies and attenuation constants of the data to find initial amplitudes and phases of n waves by selecting n solutions from the solutions of each order m according to a predetermined method and applying the fitting method thereto;
- ii) calculating Akaike's information criterion, AIC (m, n), from the parameters m and n by successively substituting the values of the n waves according to the method of selection;
- iii) finding a combination for order m.sub.o and the number of solutions n.sub.o which minimize the AIC (m, n);
- iv) selecting substituted n.sub.0 solutions from the solutions of the order m.sub.o ;
- and
- d) displaying the selected solutions as a noise free frequency spectrum.
6 more elements
A spectroscopy method comprising:
- (a) producing an output signal being the output of a spectrometer, said signal comprising the summation of signals of multiple frequencies;
- (b) digitizing and sampling the two components of the output signal which are .pi./2 radians out-of-phase at spaced time intervals to produce time series data;
- (c) converting the time series data to a frequency spectrum by finding frequencies and attenuation constants of wave elements by use of an autoregressive model comprising:
- i) comparing the powers or the initial amplitudes of waves of the same order m of the autoregressive model with respect to the solutions of each order m and sorting the solutions in descending order of powers or the initial amplitudes for the waves of each order m;
- ii) selecting n solutions successively from the solutions of each order m according to the sequencing and applying the least squares method to the time series data using the frequencies and the attenuation constants of n waves of the signal to find the initial amplitudes and the phases of the n waves;
- iii) calculating Akaike's information criterion, AIC (m, n) from the parameters m and n by successively substituting the values of the n waves according to the sequencing;
- iv) finding a combination of order m.sub.o and the number of solutions n.sub.o which minimizes the AIC (m, n);
- v) selecting n.sub.o solutions of upper orders from the solutions of the order m.sub.o according to the sequencing;
- d) displaying the selected solutions as a noise free frequency spectrum.
6 more elements
Dependencies are inferred from the claim text.