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US 5,294,655 AGranted
Polyphenylene ether electrical insulation compositions
AssigneeGeneral Electric Company
InventorsGim F. Lee, Jr., Kevin M. Snow
Life of this patent
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Abstract
Improved thermoplastic compositions characterized by high tensile elongation values are described. They comprise polyphenylene ether resin, a hydrogenated elastomeric block copolymer having an A-B-A' structure, with specific molecular weight values for the copolymer blocks and a phenylsiloxane fluid of particular composition. Electrical conductor articles which include polymerized thermoplastic compositions as mentioned above represent another embodiment of this invention.
Claims16
An electrically insulative, flame retardant, thermoplastic, flexible, halogen-free composition, which comprises;
- (i) 100 parts by weight of a thermoplastic polyphenylene ether resin;
- (ii) 5 to 50 parts by weight of a phenylsiloxane fluid, said phenylsiloxane having a weight average molecular weight within the range of from about 800 to 100,000, said phenylsiloxane consisting essentially of chemically combined units of the formulae:
- (C.sub.6 H.sub.5).sub.2 SiO (a)
- CH.sub.3 (C.sub.6 H.sub.5)SiO and (b)
- (CH.sub.3).sub.2 SiO (c)
- where there is present in the phenylsiloxane fluid from 20 to 40 mole % of (a), or 40 to 80 mole % of (b), and 21 to 79 mole % of the sum of (a)+(b), based on the total moles of (a), (b), and (c);
- and
- (iii) a flexibilizing proportion of an elastomeric block copolymer having a hydrogenated A-B-A' structure, wherein A and A' are polymerized vinyl aromatic hydrocarbon blocks, and B is an ethylene-butylene bock, and
- wherein the block copolymer has a wight average molecular weight of from about 40,000 to 100,00 and the average molecular weight of each block A and ' is independently in the range of about 4,000 to about 15,000, and the weight average molecular weight of the B block is in the range of about 25,000 to about 90,000.
6 more elements
Dependencies are inferred from the claim text.