Safe acidic hard surface cleaner
AssigneeColgate-Palmolive Company
InventorsMichel Thomas, Genevieve Blandiaux, Baudouin Valange
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AssigneeColgate-Palmolive Company
InventorsMichel Thomas, Genevieve Blandiaux, Baudouin Valange
Estimating the term…
An acidic aqueous cleaner, preferably in emulsion or microemulsion form, which is of a pH in the range of one to four and is useful for cleaning hard surfaced items, such as bathtubs, sinks, tiles and porcelains and even some such items which are not acid resistant, such as those of a European enamel known as zirconium white enamel, comprises synthetic organic detergent, such as a mixture of anionic and nonionic detergents, e.g., sodium paraffin sulfonate, higher fatty alcohol ethoxylate sulfate and higher fatty alcohol or phenol ethoxylate, organic acids, e.g., mixture of succinic, glutaric and adipic acids, phosphonic acid, e.g., aminotris-(methylenephosphonic acid) and phosphoric acid in an aqueous medium. The acidic cleaner is useful to remove soap scum, lime scale and grease from surfaces of the mentioned items without adversely affecting such surfaces, and removals of the scum, scale and grease are easy, being effected by applying the microemulsion to the surface to be cleaned, followed by wiping it off. Although the cleaned surfaces may be rinsed, that is often not necessary and the surfaces will be left clean and shiny after wiping, even without rinsing, or with minimal rinsing. In the described emulsions, the organic acid components effectively remove soap scum and lime scale, the detergents remove greasy soils and promote effective contact between the acid and the surfaces to be treated, and the combination of phosphoric and phosphonic acids prevent acidic attack by the organic acid(s) on the European enamel surface being cleaned.
An acidic aqueous liquid cleaner for hard surfaced items which are acid resistant or are of zirconium white enamel and which removes lime scale, soap scum and greasy soil from surfaces of said hard surfaced items without damaging said surfaces, which comprises approximately by weight 1 to 6% of nonionic detergent(s), 2 to 8% of anionic detergent(s), organic detergent, 2 to 10% carbon atoms therein, which group of acids excludes oxalic and malonic acids, 0.01 to 2% of an aminoalkylenephosphonic acid(s) and 0.05 to 5% of phosphoric acid, with the balance being an aqueous medium, with the proportions of such aminoalkylenephosphonic, phosphoric and organic acid being in the range of 1:1-2,000:10-4,000, in which proportions the combination of aminoalkylenephosphonic and phosphoric acids prevents damage to zirconium white enamel surfaces of items to be cleaned of lime scale, soap scum and greasy soil by the detergent and organic acid.
Dependencies are inferred from the claim text.