Flourine-substituted vicinal and method for their preparation, and their use
AssigneeHoechst Aktiengesellschaft
InventorsJurgen Kulpe, Heinz Strutz
Life of this patent
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AssigneeHoechst Aktiengesellschaft
InventorsJurgen Kulpe, Heinz Strutz
Estimating the term…
Fluorine-substituted vicinal glycols of the formula ##STR1## in which the substituents R.sub.1 to R.sub.4, independently of one another, have the following meanings: R.sub.1 to R.sub.4 =H, fluorine, C.sub.1 - to C.sub.18 -alkyl in which some or all of the hydrogens may be substituted by fluorine, and at least one of the substituents R.sub.1 to R.sub.4 is a completely fluorinated alkyl or an alkyl of the formula --(CH.sub.2).sub.m --(C.sub.n F.sub.2n+1), in which m is 1 or 2, and n is an integer from 1 to 17, and x is 0 or 1. Furthermore, a method for the preparation of the fluorinated vicinal glycols is described. If the fluorinated vicinal glycols are condensed together with dicarboxylic acids, products having enhanced thermal stability are obtained.
A fluorine-substituted vicinal glycol of the formula ##STR10## in which R.sub.1 is an alkyl of the formula
A fluorine-substituted vicinal glycol consisting of 2,3-dihydroxy-5,5-bis(trifluoromethyl)bicyclo[2.2.1]heptane.
A fluorine-substituted vicinal glycol consisting of 2,3-dihydroxy-5,6,6-trifluoro-5-(trifluoromethyl)-bicyclo[2.2.1]heptane.
A fluorine-substituted vicinal glycol consisting of 2,3-dihydroxy-5-(perfluorohexyl)-bicyclo[2.2.1]-heptane.
A fluorine-substituted vicinal glycol consisting of 2,3-dihydroxy-5-(perfluorooctyl)-bicyclo[2.2.1]-heptane.
A fluorine-substituted vicinal glycol consisting of 1,2-dihydroxy-4-(perfluorohexyl)cyclohexane.
A fluorine-substituted vicinal glycol consisting of 2,3-dihydroxy-5-(2,2,3,3,4,4,5,5,6,6,7,7,7-tridecafluoroheptyl)bicyclo[2.2 .1]heptane.
A fluorine-substituted vicinal glycol consisting of 2,3-dihydroxy-5-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)bicyclo[2.2. 1]heptane.
Dependencies are inferred from the claim text.