Continuous process for the preparation of acetic anhydride or mixtures of acetic anhydride and acetic acid

Continuous process for the preparation of acetic anhydride which comprises carbonylating a mixture comprising (i) methyl iodide and (ii) methyl acetate in the presence of a rhodium catalyst and a promoter selected from lithium iodide, phosphonium iodides, ammonium iodides and heterocyclic aromatic iodides in which at least one ring hetero atom is a quaternary nitrogen atom wherein the concentration of mesityl oxide in the carbonylation mixture is suppressed by the presence therein of about 120 to 300 ppm of dissolved ferrous and/or cobaltous ion.

Process according to claim, 4 which comprises contacting carbon monoxide with a mixture comprising (i) methyl iodide, (ii) methyl acetate and (iii) acetic acid in the presence of a rhodium catalyst and a promoter selected from lithium iodide and tetraalkyl-phosphonium iodides, triphenyl(alkyl)phosphonium iodides, tetraalkylammonium iodides and N,N'-dialkyl-imidazolium iodides wherein the alkyl groups contain up to about 8 carbon atoms wherein the concentration of mesityl oxide in the carbonylation mixture is suppressed by the presence therein of about 120 to 300 ppm of dissolved ferrous ion.

Continuous process for the preparation of acetic anhydride which comprises carbonylating a mixture comprising (i) methyl iodide and (ii) methyl acetate in the presence of a rhodium catalyst and a promoter selected from lithium iodide, phosphonium iodides, ammonium iodides and heterocyclic aromatic iodides in which at least one ring hetero atom is a quaternary nitrogen atom wherein the concentration of mesityl oxide in the carbonylation mixture is suppressed by the presence therein of about 120 to 300 ppm of dissolved ferrous and/or cobaltous ion and the mixture contains less than 3 weight percent acetone.

Continuous process for the preparation of acetic anhydride which comprises carbonylating a mixture comprising (i) methyl iodide and (ii) methyl acetate and/or dimethyl ether in the presence of a rhodium catalyst and lithium iodide promoter wherein the concentration of mesityl oxide in the carbonylation mixture is suppressed by the presence therein of about 100 to 500 ppm of dissolved ferrous and/or cobaltous ion.

Continuous process for the preparation of acetic anhydride which comprises carbonylating a mixture comprising (i) methyl iodide and (ii) methyl acetate in the presence of a rhodium catalyst and lithium iodide promoter wherein the concentration of mesityl oxide in the carbonylation mixture is suppressed by the presence therein of about 120 to 300 ppm of dissolved ferrous and/or cobaltous ion.

Continuous process for the preparation of acetic anhydride which comprises carbonylating a mixture comprising (i) methyl iodide and (ii) methyl acetate and/or dimethyl ether in the presence of a rhodium catalyst and a promoter, wherein the concentration of mesityl oxide is reduced in the carbonylation mixture by the presence therein of about 100 to 500 ppm of dissolved ferrous and/or cobaltous ion.