Method for production of ethylene oxide

A method for the production of ethylene oxide by the catalytic vapor phase oxidation of ethylene with a molecular oxygen-containing gas, which method is characterized by using a vertical shell-and-tube exchanger type reactor comprising a shell plate, an upper tube plate, a lower tube plate, a partition plate for separating a shell side of a reaction zone and a shell side of a cooling zone, and a multiplicity of reaction tubes and a preheating zone having the inlet of the reaction tubes packed with an inert packing, a reaction zone having the reaction tubes packed with a silver catalyst between the inlet and the outlet thereof, and a cooling zone having the outlet of the reaction tubes packed with an inert packing and

• effecting the production by
• supplying hot water at a temperature in the range between 100.degree. C. and 150.degree. C. through a first hot water supply conduit to the cooling zone,
• where said hot water contacts the exteriors of said reaction tubes containing a reaction product gas at a temperature in the range between 200.degree. C. and 300.degree. C. in said cooling zone, and exchanges heat with the reaction product gas containing ethylene, ethylene oxide, and oxygen, and assumes a temperature in the range between 200.degree. C. and 250.degree. C. causing a first portion of said hot water to be forwarded through a first hot water discharge conduit to a gas-liquid separation tank,
• circulating the remainder of said hot water by a pump to said cooling part,
• introducing the hot water separated in said gas-liquid separation tank through a second hot water supply conduit to said reaction zone, allowing the introduced hot water to contact the outer sides of the reaction tubes of the reaction zone to remove the heat of the reaction, and
• bringing into contact with the exteriors of said reaction tubes in said preheating zone the remainder portion of hot water which has contacted the exteriors of said reaction tubes in said reaction zone, absorbed the heat of reaction, and assumed the boiled state of a gas-liquid mixed phase in said reaction zone
• thereby preheating raw material gas and inducing spontaneous circulation of said gas-liquid mixed phase through a second hot water discharge conduit to said gas-liquid separation tank.