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US 5,292,806 AGranted
Compositions containing blends of polystyrene-polyisoprene-polystyrene block copolymers
AssigneesThe Dow Chemical Company, Exxon Chemical Patents Inc.
InventorsCharles F. Diehl, Jean M. Tancrede
Life of this patent
Estimating the term…
Abstract
Blends of low styrene content polystyrene-polyisoprene-polystyrene block copolymer and high styrene content polystyrene-polyisoprene-polystyrene block copolymer can be used with tackifier resins, plasticizer oil and antioxidants to formulate pressure sensitive adhesives of improved cohesive strength vis-a-vis adhesives formed from the low styrene content polystyrene-polyisoprene-polystyrene block copolymer while maintaining good balance between tack, bonding characteristics and heat resistance.
Claims11
A composition of matter which comprises
- a blend of A-B-A block copolymers, where the A component of each block copolymer of the blend is polystyrene and the B component is polyisoprene, said blend including
- A) a first A-B-A block copolymer having an overall number average molecular weight ranging from about 90,000 to about 250,000, wherein the polyisoprene has a number average molecular weight ranging from about 80,000 to about 225,000, the polystyrene block has a number average molecular weight ranging from about 8,000 to about 17,000 and the overall styrene content of the block copolymer ranges from about 10 percent to about 24 percent, and
- B) a second A-B-A block copolymer having an overall number average molecular weight ranging from about 60,000 to about 110,000, wherein the polyisoprene has a number average molecular weight ranging from about 30,000 to about 70,000, the polystyrene block has a number average molecular weight ranging from about 12,000 to about 20,000, and the overall styrene content of the block copolymer ranges from about 25 percent to about 50 percent,
- from about 40 parts to about 95 parts of the first A-B-A block copolymer,
- from about 5 parts to about 60 parts of the second A-B-A block copolymer,
- from about 80 parts to about 225 parts of compatible primary tackifying resin, or resins, per 100 parts by weight of the blend of block copolymers, and
- from about 0.1 percent to about 2 percent of a stabilizer, based on the weight of the total composition.
4 more elements
Dependencies are inferred from the claim text.