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US 5,292,764 AGranted
Azole derivatives for protecting industrial materials from bacteria
AssigneeKureha Kagaku Kogyo Kabushiki Kaisha
InventorsMasato Arahira, Toshihide Saishoji, Katsuhisa Ohsugi, Satoru Kumazawa
Life of this patent
Estimating the term…
Abstract
Disclosed herein is a method for preventing deterioration of an industrial material by using an azole derivative represented by the following formula ##STR1## wherein X means a halogen atom or a C.sub.1 -C.sub.5 alkyl, haloalkyl, phenyl, cyano or nitro group, n stands for 0 or an integer of 1-5, A denotes a nitrogen atom or CH, R.sub.1 and R.sub.2 mean individually a hydrogen atom or a C.sub.1 -C.sub.5 alkyl group, R.sub.3 denotes a hydrogen atom or a C.sub.1 -C.sub.3 alkyl group, and when n is an integer of 2-5, Xs may be the same or different. A biocidal composition for the method is also disclosed.
Claims6
A treated industrial material resistant to deterioration by bacteria noxious to the untreated industrial material,
- wherein the industrial material is selected from the group consisting of paper, pulp, fibers, leather, rubber and synthetic resins;
- said industrial material having been treated with a triazole derivative in an amount which renders said industrial material bactericidally resistant to deterioration by said bacteria, said triazole derivative being a compound represented by the following formula (I):
- ##STR8## wherein X.sub.1 and X.sub.2 individually are selected from the group consisting of a hydrogen atom, a halogen atom, and C.sub.1 -C.sub.4 alkyl, phenyl and cyano groups, R.sub.1 and R.sub.2 individually are selected from the group consisting of a hydrogen atom and C.sub.1 -C.sub.5 alkyl groups, and R.sub.3 is selected from the group consisting of a hydrogen atom and C.sub.1 -C.sub.3 alkyl groups;
- and
- wherein
- (i) when R.sub.1, R.sub.2, R.sub.3 and X.sub.1 are hydrogen atoms, X.sub.2 is selected from the group consisting of cyano, phenyl, fluorine, chlorine and bromine;
- (ii) when R.sub.1, R.sub.2 and R.sub.3 are hydrogen atoms and X.sub.1 is a fluorine atom, X.sub.2 is selected from the group consisting of fluorine and chlorine;
- (iii) when R.sub.1, R.sub.2 and R.sub.3 are hydrogen atoms and X.sub.1 is a chlorine atom, X.sub.2 is a chlorine atom;
- (iv) when R.sub.1 and R.sub.2 are individually selected from the group consisting of a hydrogen atom and C.sub.1 -C.sub.5 alkyl groups, R.sub.3 is a hydrogen atom, and X.sub.1 is a hydrogen atom, X.sub.2 is selected from the group consisting of C.sub.1 -C.sub.4 alkyl and phenyl groups, fluorine, chlorine and bromine, provided that one of R.sub.1 and R.sub.2 is not a hydrogen atom;
- (v) when R.sub.1 and R.sub.2 are individually selected from the group consisting of a hydrogen atom and C.sub.1 -C.sub.5 alkyl groups, R.sub.3 is a hydrogen atom and X.sub.1 is chlorine or fluorine, X.sub.2 is chlorine provided that one of R.sub.1 and R.sub.2 is not a hydrogen atom;
- and
- (vi) when R.sub.1 and R.sub.2 are individually a C.sub.1 -C.sub.5 alkyl group and R.sub.3 is a C.sub.1 -C.sub.3 alkyl group, X.sub.1 is a hydrogen atom and X.sub.2 is a chlorine atom.
9 more elements
A method for preventing bacterial deterioration of an industrial material,
- wherein the industrial material is selected from the group consisting of paper, pulp, fibers, leather, rubber and synthetic resins;
- which comprises applying to said industrial material a bacterial composition, said bacterial composition comprising a vehicle and a triazole derivative, said bacterial composition being applied to said industrial material in an amount which is bactericidally effective against said bacteria causing said deterioration, said triazole derivative being of the following formula (I):
- ##STR9## wherein X.sub.1 and X.sub.2 individually are selected from the group consisting of a hydrogen atom, a halogen atom, and C.sub.1 -C.sub.4 alkyl, phenyl and cyano groups, R.sub.1 and R.sub.2 individually are selected from the group consisting of a hydrogen atom and C.sub.1 -C.sub.5 alkyl groups, and R.sub.3 is selected from the group consisting of a hydrogen atom and C.sub.1 -C.sub.3 alkyl groups;
- and
- wherein
- (i) when R.sub.1, R.sub.2, R.sub.3 and X.sub.1 are hydrogen atoms, X.sub.2 is selected from the group consisting of cyano, phenyl, fluorine, chlorine and bromine;
- (ii) when R.sub.1, R.sub.2 and R.sub.3 are hydrogen atoms and X.sub.1 is a fluorine atom, X.sub.2 is selected from the group consisting of fluorine and chlorine;
- (iii) when R.sub.1, R.sub.2 and R.sub.3 are hydrogen atoms and X.sub.1 is a chlorine atom, X.sub.2 is a chlorine atom;
- (iv) when R.sub.1 and R.sub.2 are individually selected from the group consisting of a hydrogen atom and C.sub.1 -C.sub.5 alkyl groups, R.sub.3 is a hydrogen atom and X.sub.1 is a hydrogen atom, X.sub.2 is selected from the group consisting of C.sub.1 -C.sub.4 alkyl and phenyl groups, fluorine, chlorine and bromine, provided that one of R.sub.1 and R.sub.2 is not a hydrogen atom;
- (v) when R.sub.1 and R.sub.2 are individually selected from the group consisting of hydrogen atom and C.sub.1 -C.sub.5 alkyl groups, R.sub.3 is a hydrogen atom and X.sub.1 is chlorine or fluorine, X.sub.2 is chlorine provided that one of R.sub.1 and R.sub.2 is not a hydrogen atom;
- and
- (vi) when R.sub.1 and R.sub.2 are individually a C.sub.1 -C.sub.5 alkyl group and R.sub.3 is a C.sub.1 -C.sub.3 alkyl group, X.sub.1 is a hydrogen atom and X.sub.2 is a chlorine atom.
9 more elements
Dependencies are inferred from the claim text.