Production of hexabromocyclododecane

A method for brominating cyclododecatriene with bromine in a batch operation, said process comprising:

• (a) charging a reaction vessel, containing a solvent reaction media in which bromine and cyclododecatriene are substantially soluble, with a first amount of bromine, said first amount being an amount in the range from about 0.05 to about 0.6 weight percent of the stoichiometric amount of bromine needed to form hexabromocyclododecane from cyclododecatriene, based on the total amount of cyclododecatriene being brominated;
• (b) subsequent to the charging in step (a), concomitantly adding to the reaction vessel cyclododecatriene and a second amount of bromine, the respective rates of addition of said cyclododecatriene and second amount of bromine being such that, at all times during this addition, the second amount of bromine being added is within the range of from about 1 to about 10 weight percent in excess of the stoichiometric amount of bromine required to form hexabromocyclododecane from said cyclododecatriene, based on the amount of cyclododecatriene being charged to the reaction vessel.