Cathode and process for degrading halogenated carbon compounds in aqueous solvents
AssigneeCape Cod Research, Inc.
InventorsBrian G. Dixon, Leah J. Bialic
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Abstract
Aqueous solutions of halogenated carbon compounds containing at least one halogen atom and capable of undergoing nucleophilic substitution are degraded by electrolytically generating superoxide ion under the protection of a layer of ion exchange material.
Claims11
In a process for degrading wastes comprising one or more halogenated carbon compounds by the steps of providing an electrolyte cell comprising an anode, a cathode, and a source of oxygen, and impressing a voltage across said anode and cathode sufficient to reduce said oxygen at said cathode to superoxide ion, wherein the improvement comprises degrading said halogenated carbon compounds in an electrolyte comprising by volume from about 1 to 99 percent water by contacting said electrolyte with said cathode which consists essentially of an electrically conducting substrate and a heterogeneous coating said coating of which completely covers the surface of said substrate comprising two coats a and b, coat a is in contact with said substrate and containing superoxide catalyst and coat b is in contact with the electrolyte and with covering power for coat a and comprising ion exchange material.
A cathode for the degradation of halogenated carbon compounds in aqueous solution comprising an electrode made of a conductive material having coated thereon:
- an inner layer comprised of between 0.2 to 5 mg/cm.sup.2 of at least one electrode active substance with electrochemical activity for the reduction of oxygen to superoxide ion;
- an outer layer of high covering power comprised of between 1 to 15 mg/cm.sup.2 of ion exchange material.
The process for protecting superoxide ion from decomposition by water comprising electrolytically forming superoxide on a cathode coating with a layer of high covering power comprised of between 1 to 15 mg/cm.sup.2 of ion exchange material.
Dependencies are inferred from the claim text.