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US 5,290,908 AGranted
Acetylenic end-capped polyimides
AssigneeUniversity of Notre Dame du Lac
InventorGaetano F. D'Alelio
Life of this patent
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Abstract
Aromatic polyimides with acetylenic end groups are cured by coupling together thermally or catalytically using cuprous salts as catalysts to increase molecular weight with little or no by-product formation. These polyimides can be shaped and formed prior to the coupling. The acetylenic end-capped aromatic polyimides are formed by the reaction of an aromatic dianhydride, an acetylenic organic monoamine compound which will provide the reactive end groups and optionally an aromatic diamine.
Claims40
A polyimide of the formula:
- ##STR17## wherein Ar' is a tetravalent aromatic organic radical, the four carbonyl groups being attached directly to separate carbon atoms and each pair of carbonyl groups being attached to adjacent or peri carbon atoms in the Ar' radical,
- Ar is a divalent aromatic organic radical,
- R is a divalent hydrocarbon radical of 1 to 14 carbon atoms, and
- R.degree. is H or a monovalent hydrocarbon radical of 1 to 12 carbon atoms and
- n is 0 or a positive integer of at least one.
2 more elements
A polyimide of the formula:
- ##STR36## wherein n is a positive integer of at least 2.
A polyimide of the formula:
- ##STR37## wherein n is a positive integer of at least 2.
Dependencies are inferred from the claim text.