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US 5,290,859 AGranted
Thermoplastic molding materials based on polycarbonates, styrene/acrylonitrile polymers and polyolefins
AssigneeBASF SE
InventorsNorbert Niessner, Klaus Muehlbach
Life of this patent
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Abstract
Thermoplastic molding materials contain, as essential components, A) polycarbonates, B) graft polymers, C) styrene copolymers and D) polyolefins.
Claims7
A thermoplastic molding material containing, as essential components,
- A) from 10 to 88.9% by weight of at least one polycarbonate,
- B) from 30 to 70% by weight of a coarse-particled graft copolymer which has a median particle size of from 200 to 700 nm (d.sub.50 value of the integral mass distribution) and from 70 to 30% by weight of a finely divided graft copolymer which has a median particle size of from 50 to 180 nm (d.sub.50 value of the integral mass distribution) consisting of
- b.sub.1) from 40 to 80% by weight of a grafting base of an elastomeric polymer based on alkyl acrylates where the alkyl radical is of 1 to 8 carbon atoms and having a glass transition temperature below 10.degree. C. and
- b.sub.2) from 20 to 60% by weight of a graft of
- b.sub.21) from 50 to 95% by weight of styrene or a substituted styrene of the formula I ##STR3## where R is alkyl of 1 to 8 carbon atoms or hydrogen, R.sup.1 is alkyl of 1 to 8 carbon atoms and n is 0, 1, 2 or 3, or a C.sub.1 -C.sub.8 -alkyl (meth)acrylate or a mixture thereof and
- b.sub.22) from 5 to 50% by weight of acrylonitrile, methacrylonitrile, C.sub.1 -C.sub.8 -alkyl (meth)acrylates, maleic anhydride or maleimides N-substituted by C.sub.1 -C.sub.8 -alkyl or C.sub.6 -C.sub.20 -aryl groups or a mixture thereof,
- C) from 1 to 79.9% by weight of a thermoplastic copolymer of
- c.sub.1) from 50 to 95% by weight of a styrene or substituted styrene of the formula I or a C.sub.1 -C.sub.8 -alkyl (meth)acrylate or a mixture thereof and
- c.sub.2) from 5 to 50% by weight of acrylonitrile, methacrylonitrile, C.sub.1 -C.sub.8 -alkyl (meth)acrylates, maleic anhydride or maleimides N-substituted by C.sub.1 -C.sub.8 -alkyl or C.sub.6 -C.sub.20 -aryl groups or a mixture thereof,
- D) from 0.1 to 40% by weight of at least one polyolefin and
- E) from 0 to 50% by weight of a fibrous or particulate filler or a mixture thereof.
8 more elements
Dependencies are inferred from the claim text.