Compound, use and preparation
AssigneeImperial Chemical Industries PLC
InventorPeter W. Austin
Life of this patent
Estimating the term…
Abstract
A compound of the formula ##STR1## in which R.sup.1 and R.sup.2 taken together represent a polymethylene chain having 3 or 4 carbon atoms, or a polymethylene chain having 3 or 4 carbon atoms substituted by at least one lower alkyl radical having 1 to 4 carbon atoms, R.sup.3 is hydrogen, hydrocarbyl or substituted hydrocarbyl and X represents cyano, a group --SO.sub.3 M or a group --S--R.sup.4 where M is hydrogen or an alkali metal such as sodium and R.sup.4 is hydrocarbyl or substituted hydrocarbyl. Typically R.sup.1 and R.sup.2 complete a cyclopentene ring, R.sup.3 is alkyl such as methyl and X is a group --SO.sub.3 Na. The compounds have microbiological activity.
Claims23
A compound of the general formula I ##STR10## wherein R.sup.1 and R.sup.2 taken together represent a polymethylene chain having 3 or 4 carbon atoms or a polymethylene chain having 3 or 4 carbon atoms substituted by at least one lower alkyl radical having from 1 to 4 carbon atoms;
- R.sup.3 is hydrogen, hydrocarbyl or hydrocarbyl substituted with at least one atom selected from the group consisting of oxygen, nitrogen, sulphur and halogen;
- X represents cyano, a group --SO.sub.3 M or a group --S--R.sup.4 ;
- M represents a cation having a valency and being in an amount to give a neutral compound;
- and
- R.sup.4 represents hydrocarbyl or hydrocarbyl substituted with at least one atom selected from the group consisting of oxygen, nitrogen, sulphur and halogen.
A compound selected from
- 2-methylaminocarbonyl-1-thiocyanatocyclopent-1-ene,
- the sodium salt of 2-methylaminocarbonyl-1-thiosulphatocyclopent-1-ene,
- the sodium salt of 2-butylaminocarbonyl-1-thiosulphatocyclopent-1-ene,
- the sodium salt of 2-hexylaminocarbonyl-1-thiosulphatocyclopent-1-ene,
- the sodium salt of 2-octylaminocarbonyl-1-thiosulphatocyclopent-1-ene, or
- 1-tertiary butyldithio-2-methylaminocarbonylcyclopentene.
A composition comprising a carrier and a compound of general formula I ##STR12## wherein R.sup.1 and R.sup.2 taken together represent a polymethylene chain having 3 or 4 carbon atoms or a polymethylene chain having 3 or 4 carbon atoms substituted by at least one lower alkyl radical having from 1 to 4 carbon atoms;
- R.sup.3 is hydrogen, hydrocarbyl or hydrocarbyl substituted with at least one atom selected from the group consisting of oxygen, nitrogen, sulphur and halogen;
- X represents cyano, a group --SO.sub.3 M or a group --S--R.sup.4 ;
- M represents a cation having a valency and being in an amount to give a neutral compound;
- and
- R.sup.4 represents hydrocarbyl or hydrocarbyl substituted with at least one atom selected from the group consisting of oxygen, nitrogen, sulphur and halogen,
A method for inhibiting the growth of micro-organisms on, or in, a medium, which comprises treating the medium with a compound of general formula I ##STR13## wherein R.sup.1 and R.sup.2 taken together represent a polymethylene chain having 3 or 4 carbon atoms or a polymethylene chain having 3 or 4 carbon atoms substituted by at least one lower alkyl radical having from 1 to 4 carbon atoms;
- R.sup.3 is hydrogen, hydrocarbyl or hydrocarbyl substituted with at least one atom selected from the group consisting of oxygen, nitrogen, sulphur and halogen;
- X represents cyano, a group --SO.sub.3 M or a group --S--R.sup.4 ;
- M represents a cation having a valency and being in an amount to give a neutral compound;
- and
- R.sup.4 represents hydrocarbyl or hydrocarbyl substituted with at least one atom selected from the group consisting of oxygen, nitrogen, sulphur and halogen,
A method for inhibiting the growth of micro-organisms on, or in, a medium, which comprises treating the medium with a compound which is
- 2-methylaminocarbonyl-1-thiocyanatocyclopent-1-ene,
- the sodium salt of 2-methylaminocarbonyl-1-thiosulphatocyclopent-1-ene,
- the sodium salt of 2-butylaminocarbonyl-1-thiosulphatocyclopent-1-ene,
- the sodium salt of 2-hexylaminocarbonyl-1-thiosulphatocyclopent-1-ene,
- the sodium salt of 2-octylaminocarbonyl-1-thiosulphatocyclopent-1-ene, or
- 1-tertiarybutyldithio-2-methylaminocarbonylcyclopentene.
A medium susceptible to microbial attack comprising a compound having the formula ##STR14## wherein R.sup.1 and R.sup.2 taken together represent a polymethylene chain having 3 or 4 carbon atoms or a polymethylene chain having 3 or 4 carbon atoms substituted by at least one lower alkyl radical having from 1 to 4 carbon atoms;
- R.sup.3 represents hydrogen, hydrocarbyl or hydrocarbyl substituted with at least one atom selected from the group consisting of oxygen, nitrogen, sulphur and halogen,
- X represents cyano, --SO.sub.3 M or --S--R.sup.4 ;
- M represents a cation having a valency and being in an amount to give a neutral compound;
- and
- R.sup.4 represents hydrocarbyl or hydrocarbyl substituted with at least one atom selected from the group consisting of oxygen, nitrogen, sulphur and nitrogen;
- said compound of formula I being present in an amount effective to inhibit the growth of micro-organisms on, or in, said medium.
Dependencies are inferred from the claim text.