Process for regenerating a deactivated rhodium hydroformylation catalyst system
AssigneeArco Chemical Technology, L.P.
InventorTe Chang
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Abstract
A process for regenerating a deactivated hydroformylation catalyst system that contains a rhodium hydridocarbonyl tris(trisubstituted phosphine) complex, a trisubstituted phosphine, and a diphosphinoalkane, is disclosed. The process involves oxidation of the catalyst system, removal of the phosphine oxidation products, and regeneration of the catalyst system by syngas treatment, aqueous extraction, and addition of phosphine ligands.
Claims13
A process for regenerating a deactivated rhodium hydroformylation catalyst system that includes a rhodium hydridocarbonyl tris(trisubstituted phosphine) complex, a trisubstituted phosphine, and a diphosphinoalkane, said process comprising:
- (a) isolating an organic solution containing the deactivated catalyst system from an olefin hydroformylation process by separating the organic solution from an aqueous extract of aldehyde reaction products;
- (b) reacting the organic solution with an oxygen-containing gas at a temperature and for a time effective to produce a solution of oxidized catalyst system that contains less than about 5 parts per million of residual diphosphinoalkane and less than about 100 parts per million of diphosphinoalkane mono-oxidation products;
- (c) removing phosphine oxidation products from the organic solution by allowing solids to precipitate and separating the solids from the organic solution;
- and
- (d) exposing the organic solution to syngas, extracting it with water, and adding trisubstituted phosphine and diphosphinoalkane ligands in a manner and in amounts effective to form a regenerated catalyst system that has enhanced catalytic activity for hydroformylation of olefins to aldehydes compared with the deactivated catalyst system.
A process for regenerating a deactivated rhodium hydroformylation catalyst system that includes a rhodium hydridocarbonyl tris(trisubstituted phosphine) complex, a trisubstitued phosphine, and a diphosphinoalkane, said process comprising:
- (a) isolating an organic solution containing the deactivated catalyst system from an olefin hydroformylation process by separating the organic solution from an aqueous extract of aldehyde reaction products;
- (b) reacting the organic solution with an oxygen-containing gas at a temperature and for a time effective to produce a solution of oxidized catalyst system that contains less than about 5 parts per million of residual diphosphinoalkane and less than about 100 parts per million of diphosphinoalkane mono-oxidation products;
- (c) removing phosphine oxidation products from the organic solution by aqueous extraction;
- and
- (d) exposing the organic solution to syngas, extracting it with water, and adding trisubstituted phosphine and diphosphinoalkane ligands in a manner and in amounts effective to form a regenerated catalyst system that has enhanced catalytic activity for hydroformylation of olefins to aldehydes compared with the deactivated catalyst system.
A process for regenerating a deactivated rhodium hydroformylation catalyst system that includes a rhodium hydridocarbonyl tris(trisubstitued phosphine) complex, a trisubstituted phosphine, and a diphosphinoalkane, said process comprising:
- (a) isolating an organic solution containing the deactivated catalyst system from an olefin hydroformylation process by separating the organic solution from an aqueous extract of aldehyde reaction products;
- (b) reacting the organic solution with a gaseous mixture of nitrogen and oxygen that has an oxygen content within the range of about 5 to about 7 volume percent, at a temperature and for a time effective to produce a solution of oxidized catalyst system that contains less than about 5 parts per million of residual diphosphinoalkane and less than about 100 parts per million of diphosphinoalkane mono-oxidation products;
- (c) allowing solids to precipitate from the organic solution of oxidized catalyst system;
- (d) filtering the organic solution to remove the solids;
- (e) exposing the organic solution to syngas;
- (f) washing the organic solution with water;
- and
- (g) adding trisubstituted phosphine and diphosphinoalkane ligands in amounts effective to form a regenerated catalyst system that has enhanced catalytic activity for hydroformylation of olefins to aldehydes compared with the deactivated catalyst system.
Dependencies are inferred from the claim text.