Hydrosoluble/hydrodispersible polyesters and sizing of textile threads therewith
AssigneeRhone-Poulenc Chimie
InventorsEtienne Fleury, Yvette Girardeau
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AssigneeRhone-Poulenc Chimie
InventorsEtienne Fleury, Yvette Girardeau
Estimating the term…
Hydrosoluble/hydrodispersible polyester copolycondensates, well suited for the sizing of textile threads, comprise terephthalate, isophthalate, sulfoaryl dicarboxylate, ethylene glycol and polyoxyethylene glycol recurring structural units, have a glass transition temperature ranging from 15.degree. to 40.degree. C. at 85% relative humidity and the turbidity of aqueous formulations thereof are storage-stable over time; such polyester copolycondensates are conveniently prepared by (i) transesterifying admixture of dimethyl terephthalate, dimethyl sulfoaryl dicarboxylate and ethylene glycol, (ii) introducing isophthalic acid and an additional amount of ethylene glycol into the medium of transesterification and therein directly esterifying same, and (iii) polycondensing the resulting product of transesterification/direct esterification.
A hydrosoluble/hydrodispersible polyester copolycondensate comprising terephthalate, isophthalate, sulfoaryl dicarboxylate, ethylene glycol and polyoxyethylene glycol recurring structural units, having a glass transition temperature ranging from 15.degree. to 40.degree. C. at 85% relative humidity, and the turbidity of an aqueous formulation thereof being storage-stable over time.
A hydrosoluble/hydrodispersible polyester copolycondensate comprising terephthalate, isophthalate, sulfoaryl dicarboxylate, ethylene glycol and polyoxyethylene glycol recurring structural units, having a glass transition temperature ranging from 15.degree. to 40.degree. C. at 85% relative humidity, and the turbidity of an aqueous formulation thereof being storage-stable over time, said copolycondensate being formed by a process comprising (i) transesterifying an admixture of dimethyl terephthalate, dimethyl sulfoaryl dicarboxylate and ethylene glycol, (ii) introducing isophthalic acid and an additional amount of ethylene glycol into the medium of transesterification and therein directly esterifying same, and (iii) polycondensing the resulting product of such transesterification/direct esterification.
Dependencies are inferred from the claim text.