Method to monitor Meta-Paete cure on metallized substrates
AssigneeInternational Business Machines Corporation
InventorsLorraine P. McDonnell Bushnell, Judith A. Coffin, Guillermo Prada-Silva
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AssigneeInternational Business Machines Corporation
InventorsLorraine P. McDonnell Bushnell, Judith A. Coffin, Guillermo Prada-Silva
Estimating the term…
Microreflectance infrared (IR) spectroscopy is used to determine the degree of cure of Meta-Paete (pyromellitic dianhydride-oxydianiline ethyl ester) films on metallized substrates. In this method, the infrared bands at 1028 and 1015 cm.sup.-1 are used to indirectly monitor ethanol evolution during Meta-Paete cure. The 1015 cm.sup.-1 band serves as internal reference, while the 1028 cm.sup.-1 band, which corresponds to the C--O stretch in the ethoxy group, is used to monitor imidization through loss of the ethoxy group during cure. Quantification of ethanol evolution is possible, since no apparent distortion is observed in the external reflection spectra at these two frequencies. The method can also be applied to measure the cure uniformity of Meta-Paete films, to provide an estimate of film thickness over metallized substrates, and to monitor temperature uniformity in an oven cavity.
A method to non-destructively monitor the cure of meta-paete films, comprising the steps of:
A manufacturing process, comprising the steps of:
A method for monitoring temperature uniformity in an oven cavity, comprising the steps of:
Dependencies are inferred from the claim text.