Liquid softening and anti-static nonionic detergent composition with soil release promoting PET-POET copolymer
AssigneeColgate-Palmolive Company
InventorHarold E. Wixon
Life of this patent
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Abstract
A liquid softening and anti-static nonionic detergent composition comprises, as essential ingredients, a nonionic detergent, an anionic detergent, a cationic fabric softener-anti-static agent and a soil release promoting polymer of a water-soluble fraction of the polyethylene terephthalate-polyoxyethylene terephthalate type.
Claims17
A physically stable aqueous laundry detergent composition useful for washing and softening soiled fabrics comprising 10 to 50% by weight of a nonionic detergent, 1 to 30% by weight of an anionic detergent, 1 to 20% by weight of a cationic fabric softener-anti-static agent and a 0.5 to 20% by weight of a water-soluble polyethylene terephthalate-polyoxyethylene terephthalate component, which component consists essentially of a water soluble fraction of a polyethylene terephtalate-polyoxyethylene terephthalate soil release promoting polymer dispersion wherein said water-soluble fraction of a polyethylene terephthalate-polyoxyethylene terephthalate soil release promoting polymer is produced by forming a first 5-10% by weight aqueous dispersion of a polyethylene terephthalate-polyoxyethylene terephthalate copolymer having a weight average molecular weight of from about 8,000 to 60,000, wherein the polyoxyethylene has a molecular weight in the range of about 500 to 10,000, the molar ratio of polyethylene terephthalate units to polyoxyethylene terephthalate units is in the range of 2:1 to 6:1 and the proportion of ethylene oxide to phthalate moiety is at least 10:1, chilling said dispersion to produce a precipitate;
- removing said precipitate from said first aqueous dispersion to form second aqueous dispersion, and recovering said water-soluble fraction from said second aqueous dispersion.
A physically stable aqueous liquid detergent composition for cleaning and softening soiled fabrics and which can be added to the wash cycle of an automatic laundry machine, said composition comprising:
- (A) from about 10 to 50% by weight of a nonionic detergent selected from the group consisting of compounds of formulae (I) and (II):
- RO(CH.sub.2 CH.sub.2 O).sub.n H (I)
- wherein R is a primary or secondary alkyl group of from about 8 to 22 carbon atoms and n is an average of from about 5 to 20;
- ##STR11## wherein R.sub.1 is a primary or secondary alkyl group of from 4 to 12 carbon atoms and m is an average of from about 5 to 20;
- (B) from about 1 to 20% by weight of a mono-higher alkyl quaternary ammonium compound of formulae (III) or (IV):
- ##STR12## wherein R.sub.2 is a long chain aliphatic radical of from about 10 to 22 carbon atoms,
- each of the R.sub.3 's in formula (III) and the R.sub.3 in formula (IV) are independently lower alkyl or hydroxy (lower alkyl), X is a water-soluble salt-forming anion, and x and y are each positive number of at least 1 and the sum x+y is from 2 to 15;
- (C) from about 1 to 20% by weight of a sulfosuccinamate detergent co mound of the formula (V):
- ##STR13## wherein Z is a monovalent salt forming cation, R.sub.4 is hydrogen, lower alkyl, carboxyl (lower alkyl) or 1,2-dicarboxy (lower alkyl), and
- R.sub.5 is an open chain hydrocarbon of from 10 to 22 carbon atoms;
- (D) from about 0.5 to 20% by weight of a water-soluble polyethylene terephthalate-polyoxyethylene terephthalate component, which component consists essentially of a water soluble fraction of a polyethylene terephthalate-polyoxyethylene terephthalate soil release promoting polymer dispersion;
- wherein said water-soluble fraction of a polyethylene terephthalate-polyoxyethylene terephthalate soil release promoting polymer is produced by forming a first 5-10% by weight aqueous dispersion of a polyethylene terephthalate-polyoxyethylene terephthalate copolymer having a weight average molecular weight of from about 8,000 to 60,000, wherein the polyoxyethylene has a molecular weight in the range of about 500 to 10,000, the molar ratio of polyethylene terephthalate units to polyoxyethylene terephthalate units is in the range of 2:1 to 6:1 and the proportion of ethylene oxide to phthalate moiety is at least 10:1, chilling said dispersion to produce a precipitate;
- removing said precipitate from said first aqueous dispersion to form second aqueous dispersion, and recovering said water-soluble fraction from said second aqueous dispersion;
- (E) up to about 10% by weight of an anionic surfactant selected from the group consisting of linear higher alkyl aromatic sulfonates, poly (lower alkoxy) higher alkanol sulfates, olefin sulfonates and paraffin sulfonates;
- (F) up to about 3% by weight of an optical brightener;
- (G) up to about 15% by weight of an ethoxylated amine;
- (H) up to about 5% by weight of an alkaline substance;
- (I) up to about 3% by weight of enzymes;
- and
- (J) aqueous solvent carrier.
Dependencies are inferred from the claim text.