A biodegradable fabric softening composition in particulate or powder form for application to fibrous materials, so that the fabric softening component thereof is deposited on the fibrous materials and softens them, which fabric softening composition is non-toxic to aquatic organisms in waters into which waste waters containing such fabric softening component are discharged, which comprises, by weight, by weight, 1% to 25% of a fabric softening component selected from the group consisting of a higher aliphatic C12-C22 ester of pentaerythritol, an oligomer of pentaerythritol, a C2-C3 alkylene oxide derivative of an oligomer of pentaerythritol, and mixtures thereof, and 75%-99% of a clay carrier for said softening compound, said composition being essentially free of quaternary ammonium compound fabric softener.