Process for preparing chelating ion exchanger resins and the use thereof for the extraction of metals
AssigneeSchering Corporation
InventorsMichael Richter, Oliver Schumacher
Life of this patent
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Abstract
The invention relates to a process for preparing complex-forming ion exchanger resins which contain 8-hydroxyquinoline groups and can be prepared from carrier materials containing amino groups reactive with aldehydes, and aldehydes, 8-hydroxyquinoline and/or 8-hydroxyquinoline derivatives, and to the use thereof for the selective extraction of metals from aqueous solutions.
Claims10
A process for the extraction of metals comprising extracting metal ions from an aqueous solution by passing said solution through an ion exchange resin, said ion exchange resin prepared by a process which includes the steps of (a) preparing a carrier material by amidoalkylation or imidoalkylation of a crosslinked styrene copolymer with an ester or an ether of an N-hydroxyalkylimide followed by subsequent hydrolysis of the amido- or imido-alkylation product;
- (b) reacting said carrier material with an aldehyde and 8-hydroxyquinoline and/or an 8-hydroxy-quinoline derivative and, optionally, a swelling agent and/or a solvent, said reaction occurring at a temperature of between 20.degree. C. and 100.degree. C.;
- and (c) washing the reaction product of step (b) with water and, optionally, an acid or a base and/or a solvent.
Dependencies are inferred from the claim text.