Crosslinked polyester amide membranes and their use for organic separations

A method for separating mixtures of organic liquids into their components, said separation process comprising contacting the organic liquid mixture to be separated into its components with one side of a supported crosslinked polyester amide interfacially polymerized membrane made by the process comprising reacting a dianhydride or its corresponding tetra-acid or diacid-diester with a polyester diol in a 2:1 to 1.05:1 mole ratio of anhydride or carboxylic acid groups to polyester hydroxyl groups, to produce an endcapped prepolymer, reacting the endcapped prepolymer with excess thionyl chloride to convert all unreacted anhydride or carboxylic acid groups into acid chloride groups, dissolving the resulting acid chloride derivative in an organic solvent that is substantially immiscible with water, dissolving a diamine in water to produce an aqueous diamine solution contacting the aqueous diamine solution with the acid-chloride derivative organic solvent solution so that the organic and aqueous solutions float one upon the other with an interface between them whereby the membrane forms at said interface due to the reaction between the diamine and acid chloride capped prepolymer in the respective solutions drying the membrane at between 50.degree. to 150.degree. C. for from 1 to 120 minutes, said separation process being conducted under pervaporation or perstraction conditions.