Poly(arylcyclobutenes)
AssigneeThe Dow Chemical Company
InventorRobert A. Kirchhoff
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Abstract
The invention is a poly(arylcyclobutene) comprising arylcyclobutene moieties connected by a bridging member, wherein the bridging member is (a) a direct bond, (b) a polyvalent inorganic radical or (c) a polyvalent organic radical which contains (1) one or more heteroatoms comprising oxygen, sulfur, nitrogen or phosphorus or (2) one or more aromatic radicals, and wherein one or more cyclobutene rings are fused to one of the aryl rings.
Claims55
A poly(arylcyclobutene) which corresponds to the formula ##STR68## wherein B is a single direct bond between the Ar moieties or a sole bridging member between the Ar moieties which contains (1) a polyvalent inorganic radical, or (2) a polyvalent organic radical containing (a) one or more heteroatoms comprising oxygen, sulfur, nitrogen, silicon, or phosphorus, or (b) one or more aromatic radicals;
- with the proviso that B is not ##STR69## wherein X is a hydrocarbon poly-yl radical or a hydrocarbon poly-yl radical which contains a heteroatom;
- R is separately in each occurrence hydrogen, an electron-withdrawing substituent or an electron-donating substituent;
- Ar is an aromatic radical or an aromatic radical substituted with an electron-withdrawing substituent or electron-donating substituent provided that (1) where B is a polyvalent inorganic radical or a polyvalent organic radical, B is bonded to each Ar by a single bond and (2) the carbons of the cyclobutene ring ##STR70## are bonded to adjacent carbon atoms on the same aromatic ring or Ar;
- m is an integer of 1 or greater;
- and
- n is an integer of 2 or greater;
- provided that B can be a direct bond only when n is equal to 2 and further provided that the poly(arylcyclobutene) be polymerizable through opening of the cyclobutene rings.
Dependencies are inferred from the claim text.