Transition metal-spirobenzopyran complex, a production process therefor and a photochromic material comprising the complex
AssigneeOtsuka Kagaku Kabushiki Kaisha
InventorAkira Miyashita
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Abstract
The object of the invention is to provide a novel compound exhibiting stable photochromism. The invention is directed to a transition metal-spirobenzothiopyran complex of the general formula ##STR1## wherein R.sup.1 for example be C.sub.1-20 alkyl; R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7 and R.sup.8 independently may mean hydrogen; Y means O or S; M may for example be Cr, and a process for producing the complex.
Claims3
A transition metal-spirobenzopyran complex of the general formula ##STR11## wherein R.sup.1 means an alkyl group of 1 to 20 carbon atoms or an aralkyl group. R.sup.2, R.sup.3, R.sup.4, and R.sup.5 may be the same or different and each means a hydrogen atom, an alkyl group of 1 to 6 carbon atoms, an aryl group, an aralkyl group, an alkoxy group of 1 to 5 carbon atoms, a halogen atom, a cyano group or a nitro group. R.sup.6 and R.sup.7 may be the same or different and each means a hydrogen atom, an alkyl group of 1 to 6 carbon atoms, an aryl group, an aralkyl group, a halogen atom, a cyano group or a nitro group. R.sup.8 means a hydrogen atom, an alkyl group of 1 to 6 carbon atoms, an alkoxy group or 1 to 5 carbon atoms, a chloromethyl group, a methacryloxymethyl group or a vinyl group. Y means a oxygen atom or a sulfur atom. M means a chromium atom, a molybdenum atom or a tungsten atom.
Dependencies are inferred from the claim text.